Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Nitroxide-mediated radical polymerization: limitations and versatility
RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …
has been widely adopted for the preparation of a panoply of new polymer architectures …
Kinetic subtleties of nitroxide mediated polymerization
D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …
lot of investigations have focused on the kinetics of this process. During the last decade …
Scavenging of organic C-centered radicals by nitroxides
EG Bagryanskaya, SRA Marque - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION For more than two decades, from the 1960s to the mid-1980s,
fundamental research in radical chemistry aroused tremedeous interest in the physical …
fundamental research in radical chemistry aroused tremedeous interest in the physical …
New insights into the mechanism of amine/nitroxide cycling during the hindered amine light stabilizer inhibited oxidative degradation of polymers
G Gryn'ova, KU Ingold, ML Coote - Journal of the American …, 2012 - ACS Publications
High-level ab initio molecular orbital theory calculations are used to identify the origin of the
remarkably high inhibition stoichiometric factors exhibited by dialkylamine-based radical …
remarkably high inhibition stoichiometric factors exhibited by dialkylamine-based radical …
Nitroxide‐mediated polymerization of methacrylic esters: insights and solutions to a long‐standing problem
E Guégain, Y Guillaneuf… - Macromolecular rapid …, 2015 - Wiley Online Library
Nitroxide‐mediated polymerization (NMP) is one of the most powerful reversible
deactivation radical polymerization techniques and has incredibly gained in maturity and …
deactivation radical polymerization techniques and has incredibly gained in maturity and …
MAMA-SG1 initiated nitroxide mediated polymerization of styrene: From Arrhenius parameters to model-based design
SK Fierens, DR D'hooge, PHM Van Steenberge… - Chemical Engineering …, 2015 - Elsevier
Activation and deactivation Arrhenius parameters are estimated for nitroxide mediated
polymerization (NMP) of styrene initiated by BlocBuilder MA, based on an extensive set of …
polymerization (NMP) of styrene initiated by BlocBuilder MA, based on an extensive set of …
[HTML][HTML] Smart control of nitroxide-mediated polymerization initiators' reactivity by pH, complexation with metals, and chemical transformations
M Edeleva, G Audran, S Marque, E Bagryanskaya - Materials, 2019 - mdpi.com
Because alkoxyamines are employed in a number of important applications, such as
nitroxide-mediated polymerization, radical chemistry, redox chemistry, and catalysis …
nitroxide-mediated polymerization, radical chemistry, redox chemistry, and catalysis …
New method for the synthesis of heterospin metal complexes with nitroxides
VI Ovcharenko, OV Kuznetsova - Russian Chemical Reviews, 2020 - iopscience.iop.org
A new approach was developed to synthesize transition metal complexes with nitroxides
based on the simultaneous involvement of nitronyl nitroxide and imino nitroxide in the …
based on the simultaneous involvement of nitronyl nitroxide and imino nitroxide in the …
Which side-reactions compromise nitroxide mediated polymerization?
The mechanism of the nitroxide mediated polymerization (NMP) is well understood, however
less is known about the side-reactions that interfere and in certain cases severely …
less is known about the side-reactions that interfere and in certain cases severely …