Palladium (II)‐catalyzed C H activation/C C cross‐coupling reactions: versatility and practicality

X Chen, KM Engle, DH Wang… - Angewandte Chemie …, 2009 - Wiley Online Library
Pick your Pd partners: A number of catalytic systems have been developed for palladium‐
catalyzed C H activation/C C bond formation. Recent studies concerning the palladium …

Palladium (II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit

X Chen, KM Engle, DH Wang, JQ Yu - Angewandte Chemie, 2009 - Wiley Online Library
Abstract Katalyse mit Methode: Eine ganze Reihe katalytischer Palladiumsysteme für die C‐
H‐Aktivierung/C‐C‐Kupplung (siehe Schema) wurde in jüngerer Zeit entwickelt. Ein …

Organocatalytic enantioselective desymmetrisation

A Borissov, TQ Davies, SR Ellis, TA Fleming… - Chemical Society …, 2016 - pubs.rsc.org
Organocatalytic enantioselective desymmetrisation of achiral or meso compounds is a
powerful strategy for the construction of enantiomerically enriched complex molecules, often …

Organocatalytic Enantioselective Acyl Transfer onto Racemic as well as meso Alcohols, Amines, and Thiols

CE Müller, PR Schreiner - Angewandte Chemie International …, 2011 - Wiley Online Library
Acyl transfer is at the heart of functional‐group transfers utilized both in nature and in the
chemical laboratory. Acylations are part of the natural assembly machinery for the …

Kinetic Resolution of 1, 1′‐Biaryl‐2, 2′‐Diols and Amino Alcohols through NHC‐Catalyzed Atroposelective Acylation

S Lu, SB Poh, Y Zhao - Angewandte Chemie International …, 2014 - Wiley Online Library
We present here a highly efficient NHC‐catalyzed kinetic resolution of a wide range of 1, 1′‐
biaryl‐2, 2′‐diols and amino alcohols to provide them in uniformly≥ 99% ee. This …

Cu (I)-catalyzed chemo-and enantioselective desymmetrizing C–O bond coupling of acyl radicals

ZL Yu, YF Cheng, JR Liu, W Yang, DT Xu… - Journal of the …, 2023 - ACS Publications
Transition-metal-catalyzed enantioselective functionalization of acyl radicals has so far not
been realized, probably due to their relatively high reactivity, which renders the chemo-and …

Different strategies for designing dual-catalytic enantioselective processes: from fully cooperative to non-cooperative systems

F Romiti, J Del Pozo, PHS Paioti… - Journal of the …, 2019 - ACS Publications
An emerging area of research in chemistry requires that we learn how to manage the
characteristics of a pair of co-catalysts so that a transformation proceeds as we wish it to …

Regioselective, borinic acid-catalyzed monoacylation, sulfonylation and alkylation of diols and carbohydrates: expansion of substrate scope and mechanistic studies

D Lee, CL Williamson, L Chan… - Journal of the American …, 2012 - ACS Publications
Synthetic and mechanistic aspects of the diarylborinic acid-catalyzed regioselective
monofunctionalization of 1, 2-and 1, 3-diols are presented. Diarylborinic acid catalysis is …

Combinatorial transition‐metal catalysis: mixing monodentate ligands to control enantio‐, diastereo‐, and regioselectivity

MT Reetz - Angewandte Chemie International Edition, 2008 - Wiley Online Library
This review focuses on a new approach to combinatorial homogeneous transition‐metal
catalysis which goes beyond the traditional parallel preparation of modular ligands. It is …

Increasing the reactivity of nitrogen catalysts

N De Rycke, F Couty, ORP David - Chemistry–A European …, 2011 - Wiley Online Library
This review article presents how nitrogen‐centred Lewis bases were modified in order to
increase their reactivity in catalytic processes. As examples, we focus on alcohol acylation …