Spatially resolved analysis of short-range structure perturbations in a plastically bent molecular crystal
The exceptional mechanical flexibility observed with certain organic crystals defies the
common perception of single crystals as brittle objects. Here, we describe the …
common perception of single crystals as brittle objects. Here, we describe the …
Ultrathin inorganic molecular nanowire based on polyoxometalates
Z Zhang, T Murayama, M Sadakane, H Ariga… - Nature …, 2015 - nature.com
The development of metal oxide-based molecular wires is important for fundamental
research and potential practical applications. However, examples of these materials are …
research and potential practical applications. However, examples of these materials are …
π-Stacked Ion Pairs: Tightly Associated Charged Porphyrins in Ordered Arrangement Enabling Radical-Pair Formation
H Tanaka, Y Kobayashi, K Furukawa… - Journal of the …, 2022 - ACS Publications
π-Electronic ion pairs are of interest for fabricating electronic materials that use
intermolecular interactions based on electrostatic and dispersion forces, defined as i π–i π …
intermolecular interactions based on electrostatic and dispersion forces, defined as i π–i π …
Comparison of the magnetic anisotropy and spin relaxation phenomenon of dinuclear terbium (III) phthalocyaninato single-molecule magnets using the geometric spin …
T Morita, M Damjanović, K Katoh… - Journal of the …, 2018 - ACS Publications
Herein we report the synthesis and characterization of a dinuclear TbIII single-molecule
magnet (SMM) with two [TbPc2] 0 units connected via a fused-phthalocyaninato ligand. The …
magnet (SMM) with two [TbPc2] 0 units connected via a fused-phthalocyaninato ligand. The …
Partial Charge Transfer in the Shortest Possible Metallofullerene Peapod, La@C82⊂[11]Cycloparaphenylene
T Iwamoto, Z Slanina, N Mizorogi, J Guo… - … A European Journal, 2014 - Wiley Online Library
Cycloparaphenylene ([11] CPP) selectively encapsulates La@ C82 to form the shortest
possible metallofullerene–carbon nanotube (CNT) peapod, La@ C82⊂[11] CPP, in solution …
possible metallofullerene–carbon nanotube (CNT) peapod, La@ C82⊂[11] CPP, in solution …
Deprotonation-Induced and Ion-Pairing-Modulated Diradical Properties of Partially Conjugated Pyrrole–Quinone Conjunction
S Sugiura, T Kubo, Y Haketa, Y Hori… - Journal of the …, 2023 - ACS Publications
Q uinoidal molecules based on di p yrrolyldiketone b oron complexes (QPB s), in which
pyrrole units were connected by a partially conjugated system as a singlet spin coupler …
pyrrole units were connected by a partially conjugated system as a singlet spin coupler …
Ion-pairing π-electronic systems: ordered arrangement and noncovalent interactions of negatively charged porphyrins
Y Sasano, H Tanaka, Y Haketa, Y Kobayashi… - Chemical …, 2021 - pubs.rsc.org
In this study, charged π-electronic species are observed to develop stacking structures
based on electrostatic and dispersion forces. iπ–iπ Interaction, defined herein, functions for …
based on electrostatic and dispersion forces. iπ–iπ Interaction, defined herein, functions for …
Tetrahedral connection of ε-keggin-type polyoxometalates to form an all-inorganic octahedral molecular sieve with an intrinsic 3D pore system
Z Zhang, M Sadakane, T Murayama, S Izumi… - Inorganic …, 2014 - ACS Publications
A new type of polyoxometalate-based porous material was successfully synthesized. The
new material is the first fully inorganic Keggin-type polyoxometalate-based microporous …
new material is the first fully inorganic Keggin-type polyoxometalate-based microporous …
Redox Treatment of Orthorhombic Mo29V11O112 and Relationships between Crystal Structure, Microporosity and Catalytic Performance for Selective Oxidation of …
S Ishikawa, D Kobayashi, T Konya… - The Journal of …, 2015 - ACS Publications
Redox treatments of an orthorhombic Mo29V11O112 catalyst (MoVO) were conducted and
its crystal structure, microporosity, and catalytic activity were investigated. TPR and TG …
its crystal structure, microporosity, and catalytic activity were investigated. TPR and TG …
π‐Electron Systems That Form Planar and Interlocked Anion Complexes and Their Ion‐Pairing Assemblies
R Yamakado, T Sakurai, W Matsuda… - … A European Journal, 2016 - Wiley Online Library
Interactions between designed charged species are important for the ordered arrangements
of π‐electron systems in assembled structures. As precursors of π‐electron anion units, new …
of π‐electron systems in assembled structures. As precursors of π‐electron anion units, new …