Metallothioneins (MTs) define a superfamily of ubiquitous cysteine-rich low molecular weight
proteins or polypeptides that contain polynuclear metalsulfur coordination sites formed by …

Thiolates are presently a subject of great interest in the chemistry of complexes involving
transition‐metal elements and soft ligands. The manifold electronic and steric capabilities …

2. DESCRIPTION OF MOLECULAR STRUCTURE TYPES........... 1040 2.1. Monometallic
structures....................... 1040 2.2. Bimetallic structures........................ 1045 2.3. Trimetallic …

Cuprous-thiolate multimetallic clusters exist in a range of different biological molecules for
which no structural information exists from X-ray crystallography. Spectroscopic toolssuch as …

The synthesis of a range of new compartmental macrocyclic complexes based on 2, 6-
diformyl and-diketo phenol groups is described. The metal-free ligands have been prepared …

The Wilson disease copper-transporting ATPase plays a critical role in the intracellular
trafficking of copper. Mutations in this protein lead to the accumulation of a toxic level of …

Evolvement of the metal complex chemistry of thiolates, a fundamental ligand type, has
proceeded so rapidly, particularly over the last half-dozen years, that our knowledge of …

Unter den Komplexen der Übergangsmetalle mit weichen Liganden spielen die Thiolate
eine wichtige und aktuelle Rolle. Durch die vielfältigen elektronischen und sterischen …

Assembly of functional cytochrome oxidase in yeast requires Cox17, which has been
postulated to deliver copper ions to the mitochondrion for insertion into the enzyme. This role …

Analogous hexanuclear, paddlewheel complexes are formed by reaction of Ag I and Cu I
precursors with the new ligand 3‐tri‐methylsilyl‐2‐pyridinethiol. MS 2 N coordination has …