Chemical composition and architecture are two key factors that control the physical and
material properties of polymers. Some of the more unusual and intriguing polymer …

One of the most important objectives in materials, chemical, and physical sciences is the
creation of large conjugated macrocycles with well‐defined shapes, since such molecules …

Enzymes are nanometer-sized molecules with three-dimensional structures created by the
folding and self-assembly of polymeric chain-like components through supramolecular …

A simple self‐assembled [Pd2L4] coordination cage consisting of four carbazole‐based
ligands was found to dimerize into the interpenetrated double cage [3 X@ Pd4L8] upon the …

Molecular encapsulation processes under the control of an external trigger play a major role
in biological signal transduction processes and enzyme catalysis. Here, we present an …

A novel chelated ruthenium-based metathesis catalyst bearing an N-2, 6-diisopropylphenyl
group is reported and displays near-perfect selectivity for the Z-olefin (> 95%), as well as …

Macrocyclic hosts with a well‐defined cavity are particularly appealing for supramolecular
chemistry, but they are still rare. In this research, we reported a new class of macrocyclic …

The first report of Z-selective macrocyclizations using a ruthenium-based metathesis catalyst
is described. The selectivity for Z macrocycles is consistently high for a diverse set of …

Discrete metal-carboxylate cage-like materials are an important class of metal-organic
polyhedra. The designs of these self-assemblies in terms of their characteristic polygonal …

A recently discovered anion receptor is jointed by three related macrocycles differing in the
number of glycoluril units and type of substitution. The synthesis is carried out in nonpolar …