Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Electrohalogenation of organic compounds

MR Scheide, CR Nicoleti, GM Martins… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Herein, we present an overview of recent advances in the electrochemical halogenation of
organic compounds. Halogen-containing compounds are essential building blocks for post …

Kinetics and mechanism of plasmon-driven dehalogenation reaction of brominated purine nucleobases on Ag and Au

A Dutta, R Schürmann, S Kogikoski Jr… - ACS …, 2021 - ACS Publications
Plasmon-driven photocatalysis is an emerging and promising application of noble metal
nanoparticles (NPs). An understanding of the fundamental aspects of plasmon interaction …

Electrochemical Bromofunctionalization of Alkenes and Alkynes—To Sustainability and Beyond

LG Gombos, SR Waldvogel - Sustainable Chemistry, 2022 - mdpi.com
The electrochemical generation of highly reactive and hazardous bromine under controlled
conditions as well as the reduction of surplus oxidizers and reagent waste has placed …

Electrocatalytic three-component synthesis of 4-halopyrazoles with sodium halide as the halogen source

JY Chen, HX Li, SY Mu, HY Song, ZL Wu… - Organic & …, 2022 - pubs.rsc.org
The first example of the electrocatalytic multicomponent synthesis of 4-chloro/bromo/
iodopyrazoles from hydrazines, acetylacetones and sodium halides under chemical oxidant …

Catalyst‐ and Oxidant‐Free Electrochemical Halogenation Reactions of 2H‐Indazoles with NaX (X=Cl, Br)

X Liu, Z Wu, C Feng, W Liu, M Li… - European Journal of …, 2022 - Wiley Online Library
An environmentally friendly and highly efficient electrochemical method has been
developed for halogenation of 2H‐indazoles with cheap and commercially available NaX …

Rechargeable Silicon Redox Batteries

A Epshtein, I Baskin, M Suss… - Advanced Energy …, 2022 - Wiley Online Library
Despite its high abundance and ease of production, the possibility of using silicon as an
active multivalent rechargeable anode has never been explored, until now. As a proof of …

Unusual Square Pyramidal Chalcogenide Mo5 Cluster with Bridging Pyrazolate-Ligands

IV Savina, AA Ivanov, DV Evtushok… - International Journal of …, 2023 - mdpi.com
The family of chalcogenide molybdenum clusters is well presented in the literature by a
series of compounds of nuclearity ranging from binuclear to multinuclear articulating …

Spectroelectrochemical and ESR investigation of free radicals derived from indotricarbocyanine dyes for photodynamic therapy

H Maltanava, N Belko, A Lugovski, N Brezhneva… - Dyes and …, 2022 - Elsevier
Cyclic voltammetry, UV–Vis absorption spectroscopy, and electron spin resonance are
applied to study the properties of indotricarbocyanine dyes and their radicals formed during …

Electrochemical dearomative dihydroxylation and hydroxycyclization of indoles

J Wu, R Guillot, C Kouklovsky… - Advanced Synthesis & …, 2020 - Wiley Online Library
We describe a simple and sustainable MgBr2‐mediated electrochemical dearomative
dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr2 is used in …