Review on the synthesis of dimethyl carbonate

HZ Tan, ZQ Wang, ZN Xu, J Sun, YP Xu, QS Chen… - Catalysis Today, 2018 - Elsevier
Abstract Dimethyl carbonate (DMC,(CH 3 O) 2 CO), as an important and environmentally
friendly chemical intermediate, has been widely used in industrial fields. Several large-scale …

Green Synthesis of Dimethyl Carbonate from CO2 and Methanol: New Strategies and Industrial Perspective

A Raza, M Ikram, S Guo, A Baiker… - Advanced Sustainable …, 2022 - Wiley Online Library
Dimethyl carbonate (DMC) is a commonly used and environmentally sustainable chemical
compound and intermediate in a variety of industrial applications. To date, several large …

Atomic-level insights into the steric hindrance effect of single-atom Pd catalyst to boost the synthesis of dimethyl carbonate

S Ji, Y Chen, G Zhao, Y Wang, W Sun, Z Zhang… - Applied Catalysis B …, 2022 - Elsevier
Atomic-level insight into the unique catalytic capability of single-atom catalysts that
distinguished from nanometer-sized counterparts is highly desirable for catalyst design and …

Lewis acid sites in MOFs supports promoting the catalytic activity and selectivity for CO esterification to dimethyl carbonate

YP Xu, ZQ Wang, HZ Tan, KQ Jing, ZN Xu… - Catalysis Science & …, 2020 - pubs.rsc.org
CO esterification to dimethyl carbonate (DMC) is an attractive route, although the catalyst is
the main problem restricting the industrialization of this route. Supported palladium catalysts …

Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis

HY Wu, YY Qin, YH Xiao, JS Chen, R Ye, R Guo… - Small, 2023 - Wiley Online Library
The acid–base properties of supports have an enormous impact on catalytic reactions to
regulate the selectivity and activity of supported catalysts. Herein, a train of Pd‐X‐UiO‐66 …

Synergetic effect between Pd clusters and oxygen vacancies in hierarchical Nb2O5 for lignin-derived phenol hydrodeoxygenation into benzene

S Rong, H Tan, Z Pang, Z Zong, R Zhao, Z Li… - Renewable Energy, 2022 - Elsevier
Lignin could be depolymerized into large amount of phenolic compounds via fast pyrolysis.
The upgrade of phenolic compounds via hydrodeoxygenation (HDO) involves multiple …

Elucidation of the reaction mechanism of indirect oxidative carbonylation of methanol to dimethyl carbonate on Pd/NaY catalyst: Direct identification of reaction …

C Wang, B Liu, P Liu, K Huang, N Xu, H Guo, P Bai… - Journal of …, 2022 - Elsevier
Gas-phase indirect oxidative carbonylation of methanol to dimethyl carbonate (DMC) has
been industrialized, but the reaction mechanism is still ambiguous. In this work, the reaction …

Recent progress in dimethyl carbonate synthesis using different feedstock and techniques in the presence of heterogeneous catalysts

P Kumar, VC Srivastava, UL Štangar, B Mušič… - Catalysis …, 2021 - Taylor & Francis
The present review compiles and critically evaluates studies on the synthesis of dimethyl
carbonate (DMC) using different techniques and catalysts with reaction conditions, a wide …

Linker engineering of 2D imine covalent organic frameworks for the heterogeneous palladium-catalyzed Suzuki coupling reaction

C Krishnaraj, HS Jena, KS Rawat… - … Applied Materials & …, 2022 - ACS Publications
Covalent organic frameworks (COFs) are an emerging class of porous organic polymers that
have been utilized as scaffolds for anchoring metal active species to act as heterogeneous …

CO direct esterification to dimethyl oxalate and dimethyl carbonate: the key functional motifs for catalytic selectivity

ZQ Wang, J Sun, ZN Xu, GC Guo - Nanoscale, 2020 - pubs.rsc.org
The direct esterification of CO involves processes using CO as the starting material and
ester chemicals as products. Dimethyl oxalate (DMO) and dimethyl carbonate (DMC) are two …