Molecular dynamics simulations of glassy polymers

JL Barrat, J Baschnagel, A Lyulin - Soft Matter, 2010 - pubs.rsc.org
We review recent results from computer simulation studies of polymer glasses, from the
chain dynamics around the glass transition temperature Tg to the mechanical behaviour …

Polymers and single molecule fluorescence spectroscopy, what can we learn?

D Wöll, E Braeken, A Deres, FC De Schryver… - Chemical Society …, 2009 - pubs.rsc.org
This tutorial review summarizes the most important results and developments in the field of
polymer science by means of single molecule fluorescence spectroscopy (SMFS) at ambient …

[图书][B] Glassy materials and disordered solids: An introduction to their statistical mechanics

K Binder, W Kob - 2011 - books.google.com
This book gives a pedagogical introduction to the physics of amorphous solids and related
disordered condensed matter systems. Important concepts from statistical mechanics such …

Molecular Motion in Free-Standing Thin Films of Poly(methyl methacrylate), Poly(4-tert-butylstyrene), Poly(α-methylstyrene), and Poly(2-vinylpyridine)

K Paeng, MD Ediger - Macromolecules, 2011 - ACS Publications
A photobleaching technique has been used to measure the reorientation of dilute
fluorescent probes in free-standing polymer films from 7 nm to 20 μm thick. Similar to our …

Single molecules as optical nanoprobes for soft and complex matter

F Kulzer, T Xia, M Orrit - Angewandte Chemie International …, 2010 - Wiley Online Library
The optical signals of single molecules provide information about structure and dynamics of
their nanoscale environment, free from space and time averaging. These new data are …

Optical super-resolution microscopy in polymer science

DV Chapman, H Du, WY Lee, UB Wiesner - Progress in Polymer Science, 2020 - Elsevier
The advent of optical super-resolution microscopy (OSRM) over two decades ago has
transformed light-mediated interrogation of systems down to the nanoscale. This innovative …

Heterogeneity in single-molecule observables in the study of supercooled liquids

LJ Kaufman - Annual review of physical chemistry, 2013 - annualreviews.org
Bulk approaches to studying heterogeneous systems obscure important details, as they
report average behavior rather than the distribution of behaviors in such environments …

Single‐molecule fluorescence microscopy for imaging chemical reactions: Recent progress and future opportunities for advancing polymer systems

CB Dunn, S Valdez, Z Qiang - Journal of Polymer Science, 2024 - Wiley Online Library
Single‐molecule fluorescence (smFL) imaging techniques have evolved greatly over the
past two decades to encompass the ability to monitor chemical reactions, providing unique …

Single molecule probing of the local segmental relaxation dynamics in polymer above the glass transition temperature

E Braeken, G De Cremer, P Marsal… - Journal of the …, 2009 - ACS Publications
We investigate the temporal dynamics of terrylene diimide molecule with four phenoxy rings
(TDI) in a poly (styrene)(PS) matrix in the supercooled regime by use of single molecule …

Experimental Verification of Rapid, Sporadic Particle Motions by Direct Imaging<? format?> of Glassy Colloidal Systems

JAR Fris, GA Appignanesi, ER Weeks - Physical review letters, 2011 - APS
We analyze data from confocal microscopy experiments of a colloidal suspension to validate
predictions of rapid sporadic events responsible for structural relaxation in a glassy sample …