Trends in the Diels–Alder reaction in polymer chemistry

B Briou, B Améduri, B Boutevin - Chemical Society Reviews, 2021 - pubs.rsc.org
The Diels–Alder (DA) reaction is regarded as quite a useful strategy in organic and
macromolecular syntheses. The reversibility of this reaction and the advent of self-repair …

Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications

Z Li, M Tang, S Liang, M Zhang, GM Biesold… - Progress in Polymer …, 2021 - Elsevier
Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of
applications, including supersoft elastomers, organic optoelectronics, templates for crafting …

Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Applications of orthogonal “click” chemistries in the synthesis of functional soft materials

RK Iha, KL Wooley, AM Nystrom, DJ Burke… - Chemical …, 2009 - ACS Publications
Applications for advanced functional soft materials that possess precisely engineered
properties and functional groups have been expanding significantly with the development of …

Diels–Alder “click” reactions: recent applications in polymer and material science

MA Tasdelen - Polymer Chemistry, 2011 - pubs.rsc.org
The “click” chemistry concept is based on utilizing rapid reactions which are efficient,
versatile, and selective. Indeed, Diels–Alder (DA) reactions fulfill most of the requirements …

Click chemistry beyond metal‐catalyzed cycloaddition

CR Becer, R Hoogenboom… - Angewandte Chemie …, 2009 - Wiley Online Library
No copper needed: In recent years, a large number of metal‐free click reactions have been
reported based on thiol‐ene radical additions, Diels–Alder reactions, and Michael additions …

Synthesis of functional polymers with controlled architecture by CRP of monomers in the presence of cross-linkers: From stars to gels

H Gao, K Matyjaszewski - Progress in Polymer Science, 2009 - Elsevier
Recent developments in the synthesis of functional polymers with controlled architecture
and site-specific functionality via applying controlled radical polymerization (CRP) …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

Telechelic polymers by living and controlled/living polymerization methods

MA Tasdelen, MU Kahveci, Y Yagci - Progress in Polymer Science, 2011 - Elsevier
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …

Orthogonality in organic, polymer, and supramolecular chemistry: from Merrifield to click chemistry

CH Wong, SC Zimmerman - Chemical Communications, 2013 - pubs.rsc.org
The concept of orthogonality has been applied to many areas of chemistry, ranging from
wave functions to chromatography. But it was Barany and Merrifield's orthogonal protecting …