Oxidative addition of aryl halides to a Ni (I)-bipyridine complex

SI Ting, WL Williams, AG Doyle - Journal of the American …, 2022 - ACS Publications
The oxidative addition of aryl halides to bipyridine-or phenanthroline-ligated nickel (I) is a
commonly proposed step in nickel catalysis. However, there is a scarcity of complexes of this …

Redox-Neutral, Iron-Mediated Directed C–H Activation: General Principles and Mechanistic Insights

T Zhang, WG Whitehurst, MV Pecoraro… - Journal of the …, 2024 - ACS Publications
Experimental and computational studies have been conducted and established the general
principles for enabling redox-neutral C–H activation by iron (II) complexes. The idealized …

Direct 2, 2, 2‐Trifluoro and 2, 2‐Difluoroethoxylation of a Model Macrocyclic Ar− H Substrate via Ni‐Catalysis

L Capdevila, MTGM Derks, M Montilla… - …, 2024 - Wiley Online Library
Herein, we describe the trifluoro‐and difluoroethoxylation of C (sp2)‐H bonds using nickel
(II) complexes incorporating a model macrocyclic arene substrate. Due to the coordinative …

Cyclometalated Iron and Ruthenium Complexes Supported by a Tetradentate Ligand Scaffold with Mixed O, N, and C Donor Atoms: Synthesis, Structures, and Excited …

KC Law, Z Tang, L Wu, Q Wan, WP To, X Chang… - …, 2022 - ACS Publications
A series of cyclometalated Fe (II/III) and Ru (II/III) complexes bearing a tetradentate dianionic
[O^ N^ C^ N] ligand (H2 [O^ N^ C^ N]= 2-(6-(3-(pyridin-2-yl) phenyl) pyridin-2-yl) phenol) …

Synthesis of Cytotoxic Iron‐Containing Macrocycles Through Unexpected C(sp2)−C(sp2) Bonds Formation

C Torres‐Gutiérrez… - European Journal of …, 2023 - Wiley Online Library
In previous reports, it has been demonstrated that cyclometalated iron (II/III) complexes can
be prepared by reacting iron (0) precursors and mercurated or brominated derivatives …

[PDF][PDF] DOCTORA EN CIENCIAS

DRR LE LAGADEC - 2023 - ru.dgb.unam.mx
Aunque los fármacos a base de platino han tenido un gran impacto en quimioterapia, a
menudo producen efectos secundarios severos y los tumores pueden ser inherentemente …

Organometallic Nickel Complexes Supported by Pyridinophane Ligands and Their Oxidative Reactivity

JJN Leung, DY Bae, Y Moshood, LM Mirica - 2024 - chemrxiv.org
The pyridinophane ligands RN3CX (X= H, Br) are well-established scaffolds that facilitat and
stabilize nickel oxidative addition complexes to the proximal C (aryl)–X bond. In this study …

金属-配位子協働作用とフルオロアルキル基導入反応に向けた非ホスフィン配位子を有する遷移金属錯体の合成と反応

H Dinh - oist.repo.nii.ac.jp
The thesis describes the synthesis and reactivity of metal complexes supported by
nonphosphine ligands in metal-ligand cooperation and fluoroalkyl incorporation. The first …