Hypervalent iodine compounds as environmentally friendly and relatively inexpensive
reagents have properties similar to transition metals. They are employed as alternatives to …

Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

Chiral aryliodine (III) reagents have provided an advanced concept for enantioselective
synthesis and catalysis. With the advent of chiral iodine (I/III) catalysis, many different …

A remarkable growth in hypervalent iodine‐mediated oxidative transformations as
stoichiometric reagents as well as catalysts has been well‐documented due to their …

Catalyst design has traditionally focused on rigid structural elements to prevent
conformational flexibility. Ishihara's elegant design of conformationally flexible C 2 …

The implementation of chiral iodine catalysis has tremendously been developed in the field
of asymmetric synthesis over the past decade. It enables the stereoselective creation of C–O …

The regio-and enantio-selective dearomatization of phenols has been achieved by I (I)/I (III)
catalysis enabled fluorination. The process is highly para-selective, guiding the fluoride …

Rapid development in the last decade has rendered chiral organoiodine (I/III) catalysis a
reliable methodology in asymmetric catalysis. However, due to the severely limited numbers …

A high-performance enantioselective quaternary ammonium hypoiodite catalysis was
developed for the dearomatization of arenols using oxone as an environmentally benign …

Indolizine derivatives are prevalent in many synthetic intermediates, pharmaceuticals, and
organic materials. Herein, we report a novel electro-oxidative cascade cyclization reaction …