Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere

S Wang, Y Zhao, AWH Chan, M Yao, Z Chen… - Chemical …, 2023 - ACS Publications
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …

Recent advances in understanding secondary organic aerosol: Implications for global climate forcing

M Shrivastava, CD Cappa, J Fan… - Reviews of …, 2017 - Wiley Online Library
Anthropogenic emissions and land use changes have modified atmospheric aerosol
concentrations and size distributions over time. Understanding preindustrial conditions and …

Gas-phase reactions of isoprene and its major oxidation products

PO Wennberg, KH Bates, JD Crounse… - Chemical …, 2018 - ACS Publications
Isoprene carries approximately half of the flux of non-methane volatile organic carbon
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …

Tropospheric aqueous-phase chemistry: kinetics, mechanisms, and its coupling to a changing gas phase

H Herrmann, T Schaefer, A Tilgner, SA Styler… - Chemical …, 2015 - ACS Publications
This Review aims to summarize the current understanding of bulk tropospheric aqueous-
phase chemistry. Because a complete review of all developments in this area would be …

The MCM v3. 3.1 degradation scheme for isoprene

ME Jenkin, JC Young, AR Rickard - Atmospheric Chemistry and …, 2015 - acp.copernicus.org
The chemistry of isoprene degradation in the Master Chemical Mechanism (MCM) has been
systematically refined and updated to reflect recent advances in understanding, with these …

Why do models overestimate surface ozone in the Southeast United States?

KR Travis, DJ Jacob, JA Fisher, PS Kim… - Atmospheric …, 2016 - acp.copernicus.org
Ozone pollution in the Southeast US involves complex chemistry driven by emissions of
anthropogenic nitrogen oxide radicals (NO x≡ NO+ NO 2) and biogenic isoprene. Model …

[HTML][HTML] Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol

NL Ng, SS Brown, AT Archibald, E Atlas… - Atmospheric …, 2017 - acp.copernicus.org
Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO 3)
represents one of the important interactions between anthropogenic emissions related to …

[HTML][HTML] A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol

KH Bates, DJ Jacob - Atmospheric Chemistry and Physics, 2019 - acp.copernicus.org
Atmospheric oxidation of isoprene, the most abundantly emitted non-methane hydrocarbon,
affects the abundances of ozone (O 3), the hydroxyl radical (OH), nitrogen oxide radicals …

Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO2 emission …

EA Marais, DJ Jacob, JL Jimenez… - Atmospheric …, 2016 - acp.copernicus.org
Isoprene emitted by vegetation is an important precursor of secondary organic aerosol
(SOA), but the mechanism and yields are uncertain. Aerosol is prevailingly aqueous under …

The molecular identification of organic compounds in the atmosphere: state of the art and challenges

B Noziere, M Kalberer, M Claeys, J Allan… - Chemical …, 2015 - ACS Publications
The Earth's atmosphere offers a striking contrast with other known planets by its rich organic
composition, which results almost exclusively from the presence of life on the planet. About …