Alkaloids toxic to livestock

RJ Molyneux, KE Panter - The alkaloids: chemistry and biology, 2009 - Elsevier
Plant poisonings are a major problem for livestock producers. The majority of these
episodes are due to alkaloid constituents, encompassing numerous plant species. Reviews …

Veratrum Alkaloids. XXVIII.1 The Structure and Configuration of Germine2-4

SM Kupchan, CR Narayanan - Journal of the American Chemical …, 1959 - ACS Publications
The alkaloid germine hasbeen shown to have structure and configuration I. Alkaline
isomerization of I leads to iso-germine (XI) and thence to pseudogermine (XII). Acetic …

Syntheses of isotopically labelled L-α-amino acids with an asymmetric centre at C-3

JR Harding, RA Hughes, NM Kelly… - Journal of the …, 2000 - pubs.rsc.org
Approaches are described to the synthesis of a series of isotopically labelled L-α-amino
acids each with an asymmetric centre at C-3, including isoleucine, allo-isoleucine, threonine …

Absolute configuration of the α-methylbutyryl residue in longipinene derivatives from Stevia pilosa

R Álvarez-Garcı́a, JM Torres-Valencia, LU Román… - Phytochemistry, 2005 - Elsevier
The absolute configuration of the α-methylbutyryl residue in (4R, 5S, 7S, 8S, 9S, 10R, 11R, 2
″S)-7-angeloyloxy-9-hydroxy-8-(α-methylbutyryloxy)-longipin-2-en-l-one and (4R, 5S, 7S …

Enantioselective Analysis of Methyl-Branched Alcohols and Acids in Rhubarb (Rheum rhabarbarum L.) Stalks

M Dregus, HG Schmarr, E Takahisa… - Journal of agricultural …, 2003 - ACS Publications
The enantiomeric compositions of 2-methylbutanol (1), 4-methylhexanol (2), 2-
methylbutanoic acid (3), and 4-methylhexanoic acid (4) present in rhubarb (Rheum …

Stereochemical Studies. XVI. Deaminative Acetolyses of L-valine and L-valine benzyl ester

M TANIGUCHI, K KOGA, S YAMADA - Chemical and Pharmaceutical …, 1972 - jstage.jst.go.jp
抄録 Detailed examinations were made of nitrous acid deaminations of L-valine and its
benzyl ester in acetic acid. These showed that while the substitution product is the only …

Veratrum Alkaloids. XXXIX.1 The Structures of Protoveratrine A and Protoveratrine B2,3

SM Kupchan, CI Ayres - Journal of the American Chemical …, 1960 - ACS Publications
The structures of protoveratrine A and protoveratrine B have been elucidated. Protoveratrine
A is protoverine 3-{d)-2'-hydroxy-2'-methylbutyrate 6, 7-diacetate 15-(Z)-2'-methylbutyrate …

The cevane group of Veratrum alkaloids

JV Greenhill, P Grayshan - The alkaloids: chemistry and pharmacology, 1992 - Elsevier
Publisher Summary This chapter discusses that many of the alkaloids from Veratrum,
Zygadenus and related genera are based on the cevane structure. The chemical reactions …

Simple azo dyes provide access to versatile chiroptical switches

E Anger, SP Fletcher - European Journal of Organic Chemistry, 2015 - Wiley Online Library
Azo dyes have played an important role in the development of the chemical industry for 150
years. The azo‐core of these dyes can undergo trans to cis photoisomerization, which …

Desaminierungsreaktionen, 19. Intramolekulare Reaktionen von Alkindiazoaten

W Kirmse, A Engelmann, J Heese - Chemische Berichte, 1973 - Wiley Online Library
Alkindiazoate wurden durch Spaltung der entsprechenden Nitrosoharnstoffe oder
Nitrosocarbamidsäureester mit Methanol/Methylat erzeugt. Bei Alkindiazoaten mit …