Interactions of metal− metal-bonded antitumor active complexes with DNA fragments and DNA
HT Chifotides, KR Dunbar - Accounts of chemical research, 2005 - ACS Publications
This Account summarizes the DNA binding properties of anticancer active dinuclear Rh, Re,
and Ru compounds. The combined results of NMR spectroscopy, X-ray crystallography, and …
and Ru compounds. The combined results of NMR spectroscopy, X-ray crystallography, and …
Rhodium and its compounds as potential agents in cancer treatment
N Katsaros, A Anagnostopoulou - Critical reviews in oncology/hematology, 2002 - Elsevier
The antitumor activity of the inorganic complex cis-diammine-dichloroplatinum (II)(cisplatin)
led to the development of other types of non-organic cytostatic drugs. Numerous platinum …
led to the development of other types of non-organic cytostatic drugs. Numerous platinum …
Live cell cytotoxicity studies: documentation of the interactions of antitumor active dirhodium compounds with nuclear DNA
JD Aguirre, AM Angeles-Boza, A Chouai… - Journal of the …, 2009 - ACS Publications
The promising antitumor activity of dirhodium complexes has been known for over 30 years.
There remains, however, a general lack of understanding of their activity in cellulo. In this …
There remains, however, a general lack of understanding of their activity in cellulo. In this …
1, 3-N, O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles
1, 3-N, O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral
amino acids in metalloproteins. These structural units also display diverse coordination …
amino acids in metalloproteins. These structural units also display diverse coordination …
Effect of axial coordination on the electronic structure and biological activity of dirhodium (II, II) complexes
The reactivities toward biomolecules of a series of three dirhodium (II, II) complexes that
possess an increasing number of accessible axial coordination sites are compared. In cis …
possess an increasing number of accessible axial coordination sites are compared. In cis …
Effect of Equatorial Ligands of Dirhodium(II,II) Complexes on the Efficiency and Mechanism of Transcription Inhibition in Vitro
The nature of the equatorial ligands spanning the dirhodium core was shown to affect the
ability and mechanism of various lantern-type complexes to inhibit transcription in vitro. The …
ability and mechanism of various lantern-type complexes to inhibit transcription in vitro. The …
Confocal fluorescence microscopy studies of a fluorophore-labeled dirhodium compound: visualizing metal–metal bonded molecules in lung cancer (A549) cells
The new dirhodium compound [Rh2 (μ-O2CCH3) 2 (η1-O2CCH3)(phenbodipy)(H2O)
3][O2CCH3](1), which incorporates a bodipy fluorescent tag, was prepared and studied by …
3][O2CCH3](1), which incorporates a bodipy fluorescent tag, was prepared and studied by …
Rhodium compounds
HT Chifotides, KR Dunbar - Multiple Bonds Between Metal Atoms, 2005 - Springer
Dirhodium compounds have a prominent role in the field of metal-metal bond chemistry.
Their fascinating properties span diverse fields such as catalysis, 1-5 antitumor …
Their fascinating properties span diverse fields such as catalysis, 1-5 antitumor …
The first designed syntheses of bis-dimetal molecules in which the bridges are diamidate ligands
FA Cotton, LM Daniels, JP Donahue, CY Liu… - Inorganic …, 2002 - ACS Publications
The first deliberate syntheses of molecules in which pairs of quadruply bonded Mo2 units
are bridged by N, N '-diarylterephthaloyldiamidate (aryl= Ph, m-CF3Ph) ligands are …
are bridged by N, N '-diarylterephthaloyldiamidate (aryl= Ph, m-CF3Ph) ligands are …
Amidate-Ligated Complexes of Rhodium (I): A Showcase of Coordination Flexibility
Reaction of the amidate ligand salts Na [N (Dipp) C (O) R](R= Ph (1a), t Bu (1b); Dipp= 2, 6-
diisopropylphenyl) with [Rh (NBD) Cl] 2 (NBD= norbornadiene) proceeds to give the …
diisopropylphenyl) with [Rh (NBD) Cl] 2 (NBD= norbornadiene) proceeds to give the …