Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Coenzyme NADH regeneration is crucial for sustained photoenzymatic catalysis of CO2
reduction. However, light‐driven NADH regeneration still suffers from the low regeneration …

Numerous efforts are being made toward constructing artificial nanopockets inside
heterogeneous catalysts to implement challenging reactions that are difficult to occur on …

As the main component of natural and shale gas, seabed clathrates, and biogas, methane
(CH 4) is an abundant C1 resource for added-value chemicals. CH 4 is of critical importance …

The development of efficient heterogeneous catalysts with multiselectivity (eg, enantio-and
chemoselectivity) has long been sought after but with limited progress being made so far. To …

An enzyme formulation using customized enzyme activators (metal ions) to directly construct
metal–organic frameworks (MOFs) as enzyme protective carriers is presented. These MOF …

Artificial enzymatic systems are extensively studied to mimic the structures and functions of
their natural counterparts. However, there remains a significant gap between structural …

Multi‐module design of framework materials with multiple distinct building blocks has
attracted much attention because such materials are more amenable to compositional and …