Aziridines, the smallest nitrogen-containing heterocycles, are useful building blocks in
synthesis, as well as important synthetic targets (Scheme 1). 1 The interest toward synthetic …

Electrophilic aminating reagents have seen a renaissance in recent years as effective
nitrogen sources for the synthesis of unprotected amino functionalities. Based on their …

Among the transition metals, copper-based catalyst systems enable the widest range of N-
containing reagents in C–H amination to allow for the direct incorporation of versatile N …

This review updates the recent developments in asymmetric aziridination using chiral
substrates as well as chiral catalysts, covering the literature since the beginning of 2010. It …

Summary The carbonyl azide TrocN 3 (2, 2, 2-trichloroethoxycarbonyl azide) is a potent
nitrogen radical precursor for radical olefin aziridination via Co (II)-based metalloradical …

The development of the first intermolecular Rh2 (II)-catalyzed aziridination of olefins using
anilines as nonactivated N atom precursors and an iodine (III) reagent as the stoichiometric …

Asymmetric nitrene‐transfer reactions are a powerful tool for the preparation of
enantioenriched amine building blocks. Reported herein are chemo‐and enantioselective …

Recent progress on catalytic nitrene transfer reactions with hydroxylamine derivatives as
prevalent precursors is summarized in this highlight. The salient features of these N–O …

A stereoselective Rh‐catalyzed intermolecular amination of thioethers using a readily
available chiral N‐mesyloxycarbamate to produce sulfilimines in excellent yields and …

The RhII‐catalyzed oxyamination and diamination of alkenes generate 1, 2‐amino alcohols
and 1, 2‐diamines, respectively, in good to excellent yields and with complete regiocontrol …