Gold nanofilms at liquid–liquid interfaces: an emerging platform for redox electrocatalysis, nanoplasmonic sensors, and electrovariable optics
The functionality of liquid–liquid interfaces formed between two immiscible electrolyte
solutions (ITIES) can be markedly enhanced by modification with supramolecular …
solutions (ITIES) can be markedly enhanced by modification with supramolecular …
Hydrogen Evolution, Oxygen Evolution, and Oxygen Reduction at Polarizable Liquid| Liquid Interfaces
Research on hydrogen evolution (HER), oxygen evolution (OER), and oxygen reduction
(ORR) reactions at polarizable liquid| liquid interfaces was reviewed. A number of biphasic …
(ORR) reactions at polarizable liquid| liquid interfaces was reviewed. A number of biphasic …
Gold nanofilm redox catalysis for oxygen reduction at soft interfaces
Functionalization of a soft or liquid-liquid interface by a one gold nanoparticle thick
“nanofilm” provides a conductive pathway to facilitate interfacial electron transfer from a …
“nanofilm” provides a conductive pathway to facilitate interfacial electron transfer from a …
A novel versatile microbiosensor for local hydrogen detection by means of scanning photoelectrochemical microscopy
The development of a versatile microbiosensor for hydrogen detection is reported. Carbon-
based microelectrodes were modified with a [NiFe]-hydrogenase embedded in a viologen …
based microelectrodes were modified with a [NiFe]-hydrogenase embedded in a viologen …
Hydrogen and hydrogen peroxide formation in trifluorotoluene–water biphasic systems
W Adamiak, J Jedraszko, O Krysiak… - The Journal of …, 2014 - ACS Publications
Hydrogen or hydrogen peroxide can be generated in liquid–liquid biphasic systems, where
the organic phase contains sufficiently strong electron donor (whose redox potential is lower …
the organic phase contains sufficiently strong electron donor (whose redox potential is lower …
SECM study of hydrogen photogeneration in a 1, 2-dichloroethane| water biphasic system with decamethylruthenocene electron donor regeneration
J Jedraszko, W Adamiak, W Nogala, HH Girault… - Journal of …, 2018 - Elsevier
This paper reports light driven hydrogen evolution reaction (HER) at 1, 2-dichloroethane|
water (DCE| W) interface using photoexcited decamethylruthenocene (DMRc) as electron …
water (DCE| W) interface using photoexcited decamethylruthenocene (DMRc) as electron …
Kinetic differentiation of bulk/interfacial oxygen reduction mechanisms at/near liquid/liquid interfaces using scanning electrochemical microscopy
The present work describes the application of scanning electrochemical microscopy (SECM)
in the feedback mode to determine the kinetics of oxygen reduction at or near the …
in the feedback mode to determine the kinetics of oxygen reduction at or near the …
Oxygen Absorption in Electrocatalyst Layers Detected by Scanning Electrochemical Microscopy
M Moghaddam, P Peljo - ChemElectroChem, 2021 - Wiley Online Library
Scanning electrochemical microscopy (SECM) is able to track the local electrochemical
activity of an electrolyte‐immersed substrate employing an ultra‐micro‐electrode (UME) in …
activity of an electrolyte‐immersed substrate employing an ultra‐micro‐electrode (UME) in …
H2O2 Generation at a Carbon‐Paste Electrode with Decamethylferrocene in 2‐Nitrophenyloctyl Ether as a Binder: Catalytic Effect of MoS2 Particles
J Jedraszko, O Krysiak, W Adamiak… - …, 2016 - Wiley Online Library
Here, we report hydrogen peroxide generation at the 2‐nitrophenyloctyl ether (NPOE)/water
interface with decamethylferrocene as an electron donor. The progress of this reaction was …
interface with decamethylferrocene as an electron donor. The progress of this reaction was …
Gold Nanofilm Redox Electrocatalysis for Oxygen Reduction at Soft Interfaces
E Smirnov, E Smirnov - Assemblies of Gold Nanoparticles at Liquid-Liquid …, 2018 - Springer
The interfacial reduction of oxygen by a lipophilic electron donor, decamethylferrocene,
dissolved in α, α, α-trifluorotoluene was catalyzed at a gold nanoparticle nanofilm modified …
dissolved in α, α, α-trifluorotoluene was catalyzed at a gold nanoparticle nanofilm modified …