Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

Neutral stibinyl and bismuthinyl radicals are typically short-lived, reactive species. Here we
show the synthesis and solid-state structures of two stable stibinyl [L (Cl) Ga] 2Sb· 1 and …

Abstract LGa (P2OC) cAAC 2 features a 1, 2‐diphospha‐1, 3‐butadiene unit with a
delocalized π‐type HOMO and a π*‐type LUMO according to DFT calculations.[LGa (P2OC) …

The search for main‐group element‐based radicals is one of the main research topics in
contemporary chemistry because of their fascinating chemical and physical properties. The …

Phosphorus‐centered disbiradicals, in which the radical sites exist as individual spin
doublets with weak spin‐spin interaction have not been known so far. Starting from …

Recent developments in stable radical chemistry have afforded “heavy atom” radicals,
neutral open-shell (S= 1/2) molecular species containing heavy p-block elements (S, Se) …

Abstract Singlet cyclo‐1, 3‐dipnicta‐2, 4‐diazane‐1, 3‐diyls of the type [E (μ‐NTer) 2E](2,
E= P, As, Ter= 2, 6‐dimesitylphenyl) can undergo a one‐electron‐oxidation utilizing silver …

Distonic radical cations (DRCs) with spatially separated charge and radical sites are
expected to show both radical and cationic reactivity at different sites within one molecule …

Synthesis of stable main‐group element‐based radicals represents one of the most
interesting topics in contemporary organometallic chemistry, because of their vital roles in …