Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

This article reviews prior work studying reaction kinetics in solution, with the goal of using
this information to improve detailed kinetic modeling in the solvent phase. Both experimental …

We report a transition-metal-free protocol for the efficient reductive cleavage of diaryl and
aryl alkyl ethers. The combination of triethylsilane with common bases forms an unusually …

This account describes the results of our recent mechanistic studies on unimolecular C–C
bond fragmentation (β-scission and O-neophyl rearrangement) and bimolecular hydrogen …

Arenediazonium salts are well‐known sources of aryl radicals; however, the hydroxy‐and
amino‐substituted derivatives 1, 2, and 3, which lead to the respective formation of radicals …

After lying in the doldrums during the no/low fat era, lipid oxidation is once again attracting
intense interest for its effects on food quality, stability of personal care products, impairment …

A time-resolved kinetic study on the hydrogen abstraction reactions from a series of primary
and secondary amines by the cumyloxyl (CumO•) and benzyloxyl (BnO•) radicals was …

Detailed kinetic models provide useful mechanistic insight into a chemical system. Manual
construction of such models is laborious and error-prone, which has led to the development …

A kinetic study on the hydrogen abstraction reactions from cyclic amines and diamines
(pyrrolidines, piperidines, morpholines, and piperazines) by the cumyloxyl (CumO•) and …

A kinetic study of the H-atom abstraction reactions from 1, 4-cyclohexadiene and
triethylamine by the cumyloxyl radical has been carried out in different solvents. Negligible …