This article is focused on recent developments in main group mediated hydrogenation
chemistry and catalysis using “frustrated Lewis pairs”(FLPs). The broading range of …

Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

Chiral catalysts play a crucial role in the realm of asymmetric catalysis. Since their
breakthrough discovery in 2006, chiral frustrated Lewis pairs (FLPs) have risen as a novel …

The past decade has seen the subject of transition metal-free catalytic hydrogenation
develop incredibly rapidly, transforming from a largely hypothetical possibility to a well …

Abstract Frustrated Lewis pairs (FLPs) consist of sterically hindered Lewis acids and Lewis
bases, which provide high catalytic activity towards non‐metal‐mediated activation of “inert” …

The concept of frustrated Lewis pairs (FLPs) has been widely applied in various research
areas, and metal‐free hydrogenation undoubtedly belongs to the most significant and …

C–H borylation is a powerful and atom-efficient method for converting affordable and
abundant chemicals into versatile organic reagents used in the production of fine chemicals …

Two novel frustrated Lewis pair (FLP) aminoboranes,(1-Pip-2-BH2-C6H4) 2 (2; Pip=
piperidyl) and (1-NEt2-2-BH2-C6H4) 2 (3; NEt2= diethylamino), were synthesized, and their …

Abstract The frustrated Lewis pairs (FLPs) have attracted much attention as hydrogenation
catalysts due to their metal-free properties and considerable catalytic activity. However, the …

In contrast to the established dogma that B (C6F5) 3 is irreversibly poisoned by excess
H2O/amine (or imine) bases, B (C6F5) 3 is actually a water-tolerant catalyst for the reductive …