H-and J-aggregate behavior in polymeric semiconductors

FC Spano, C Silva - Annual review of physical chemistry, 2014 - annualreviews.org
Aggregates of conjugated polymers exhibit two classes of fundamental electronic
interactions: those occurring within a given chain and those occurring between chains. The …

Interplay between intrachain and interchain interactions in semiconducting polymer assemblies: The HJ-aggregate model

H Yamagata, FC Spano - The Journal of chemical physics, 2012 - pubs.aip.org
A new model for analyzing the photophysics of polymer aggregates is introduced taking into
account exciton motion along a polymer chain and across polymer chains. Excitonic …

Determining exciton coherence from the photoluminescence spectral line shape in poly (3-hexylthiophene) thin films

FC Spano, J Clark, C Silva, RH Friend - The Journal of chemical …, 2009 - pubs.aip.org
The photoluminescence (PL) spectral line shape of regioregular poly (3-hexylthiophene)
thin films is analyzed using a model which treats the polymer π-stacks as H-aggregates with …

Length dependence for intramolecular energy transfer in three-and four-color donor− spacer− acceptor arrays

A Harriman, LJ Mallon, KJ Elliot, A Haefele… - Journal of the …, 2009 - ACS Publications
A series of donor− spacer− acceptor triads has been synthesized and fully characterized.
Both donor and acceptor units are built from boron dipyrromethene (BODIPY) dyes but they …

Local mechanical properties of electrospun fibers correlate to their internal nanostructure

A Camposeo, I Greenfeld, F Tantussi, S Pagliara… - Nano …, 2013 - ACS Publications
The properties of polymeric nanofibers can be tailored and enhanced by properly managing
the structure of the polymer molecules at the nanoscale. Although electrospun polymer …

Vibronic coupling in quantum wires: applications to polydiacetylene

H Yamagata, FC Spano - The Journal of chemical physics, 2011 - pubs.aip.org
A theory describing vibronic coupling in direct band gap, one-dimensional semiconductors
is developed to account for the photophysical properties of isolated, defect-free conjugated …

Temperature dependence of the photo-and electroluminescence of poly (p-phenylene vinylene) based polymers

I Rörich, AK Schönbein, DK Mangalore… - Journal of Materials …, 2018 - pubs.rsc.org
We show that the exciton transport and decay processes in two poly (p-phenylene
vinylene)(PPV) based semiconducting polymers exhibit distinct temperature dependence …

Photobleaching kinetics of meh-ppv in solution: the role of conformational disorder

ML Raicoski, MG Vivas - The Journal of Physical Chemistry B, 2021 - ACS Publications
Semiconductor polymers are the foundation of organic electronics due to their remarkable
optical features, ability to form a thin film, and low cost compared to silicon. However, some …

High photoluminescence quantum yield due to intramolecular energy transfer in the Super Yellow conjugated copolymer

EW Snedden, LA Cury, KN Bourdakos… - Chemical Physics …, 2010 - Elsevier
Steady-state and time-resolved photoluminescence have been used to investigate the
photophysical properties of the poly (para-phenylene vinylene) copolymer Super Yellow …

An experimental and theoretical study of the structural ordering of the PTB7 polymer at a mesoscopic scale

P Urbánek, I Kuřitka, J Ševčík, J Toušková, J Toušek… - Polymer, 2019 - Elsevier
Our extensive study based on optoelectronic and electric measurements (which consisted
of: UV–Vis absorption, photoluminescence, surface photovoltage measurement, charge …