Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Stimuli-responsive supramolecular polymeric materials

X Yan, F Wang, B Zheng, F Huang - Chemical Society Reviews, 2012 - pubs.rsc.org
Supramolecular materials, dynamic materials by nature, are defined as materials whose
components are bridged via reversible connections and undergo spontaneous and …

Weak hydrogen bonding enables hard, strong, tough, and elastic hydrogels

X Hu, M Vatankhah‐Varnoosfaderani… - Advanced …, 2015 - Wiley Online Library
DOI: 10.1002/adma. 201503724 high strength of 2 MPa, high fracture energy of 9300 J m−
2, high extensibility of 800%, excellent fatigue-resistance, and great elasticity allowing for …

Mechanically-induced chemical changes in polymeric materials

MM Caruso, DA Davis, Q Shen, SA Odom… - Chemical …, 2009 - ACS Publications
Engineering applications of synthetic polymers are widespread due to their availability,
processability, low density, and diversity of mechanical properties (Figure 1a). Despite their …

Repeatable photoinduced self‐healing of covalently cross‐linked polymers through reshuffling of trithiocarbonate units

Y Amamoto, J Kamada, H Otsuka, A Takahara… - Angewandte Chemie …, 2011 - infona.pl
Well‐healed: Polymers cross‐linked with trithiocarbonate (TTC) units were prepared by a
RAFT polymerization. The repeatable self‐healing systems or macroscopic fusions were …

Self-healing polymer films based on thiol–disulfide exchange reactions and self-healing kinetics measured using atomic force microscopy

JA Yoon, J Kamada, K Koynov, J Mohin… - …, 2012 - ACS Publications
Self-healing polymeric materials with branched architectures and reversible cross-linking
functionalities at the periphery of branches were synthesized by atom transfer radical …

Dually crosslinked polymer networks incorporating dynamic covalent bonds

L Hammer, NJ Van Zee, R Nicolaÿ - Polymers, 2021 - mdpi.com
Covalent adaptable networks (CANs) are polymeric networks containing covalent crosslinks
that are dynamic under specific conditions. In addition to possessing the malleability of …

Advances in healing-on-demand polymers and polymer composites

P Zhang, G Li - Progress in Polymer Science, 2016 - Elsevier
Healing-on-demand materials exhibit the capability to close cracks and heal the
closed/narrowed cracks when needed and to recover functionality using intrinsic or extrinsic …

Self-healing polymers and composites

TC Mauldin, MR Kessler - International Materials Reviews, 2010 - Taylor & Francis
Inspired by the unique and efficient wound healing processes in biological systems, several
approaches to develop synthetic polymers that can repair themselves with complete, or …

Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability

Y Zhao, H Wu, R Yin, C Yu, K Matyjaszewski… - Chemistry of …, 2023 - ACS Publications
The effect of sequence structure on the self-healing and shape-memory properties of
copolymer-tethered brush particle films was investigated and compared to linear copolymer …