Mixed electronic states in molecular dimers: Connecting singlet fission, excimer formation, and symmetry-breaking charge transfer
RM Young, MR Wasielewski - Accounts of chemical research, 2020 - ACS Publications
Conspectus Chromophore aggregates are capable of a wide variety of excited-state
dynamics that are potentially of great use in optoelectronic devices based on organic …
dynamics that are potentially of great use in optoelectronic devices based on organic …
Generating spin-triplet states at the bulk perovskite/organic interface for photon upconversion
CM Sullivan, L Nienhaus - Nanoscale, 2023 - pubs.rsc.org
Perovskite-sensitized triplet–triplet annihilation (TTA) upconversion (UC) holds potential for
practical applications of solid-state UC ranging from photovoltaics to sensing and imaging …
practical applications of solid-state UC ranging from photovoltaics to sensing and imaging …
Symmetry-breaking charge separation in the solid state: Tetra (phenoxy) perylenediimide polycrystalline films
Generation of electron–hole pairs via symmetry-breaking charge separation (SB-CS) in
photoexcited assemblies of organic chromophores is a potentially important route to …
photoexcited assemblies of organic chromophores is a potentially important route to …
Triplet Formation in a 9, 10-Bis (phenylethynyl) anthracene Dimer and Trimer Occurs by Charge Recombination Rather than Singlet Fission
R Ringström, ZW Schroeder… - The Journal of …, 2023 - ACS Publications
We present an experimental study investigating the solvent-dependent dynamics of a 9, 10-
bis (phenylethynyl) anthracene monomer, dimer, and trimer. Using transient absorption …
bis (phenylethynyl) anthracene monomer, dimer, and trimer. Using transient absorption …
Balancing charge transfer and Frenkel exciton coupling leads to excimer formation in molecular dimers: Implications for singlet fission
Photoexcitation of molecular chromophore aggregates can form excimer states that play a
significant role in photophysical processes such as charge and energy transfer as well as …
significant role in photophysical processes such as charge and energy transfer as well as …
Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths
J Isokuortti, T Griebenow, JS von Glasenapp… - Chemical …, 2023 - pubs.rsc.org
Diazocines are bridged azobenzenes with phenyl rings connected by a CH2–CH2 group.
Despite this rather small structural difference, diazocine exhibits improved properties over …
Despite this rather small structural difference, diazocine exhibits improved properties over …
Recharging upconversion: revealing rubrene's replacement
CM Sullivan, L Nienhaus - Nanoscale, 2022 - pubs.rsc.org
One of the major limitations of solid-state perovskite-sensitized photon upconversion to date
is that the only annihilator successfully paired with the perovskite sensitizer has been …
is that the only annihilator successfully paired with the perovskite sensitizer has been …
Spin dynamics of quintet and triplet states resulting from singlet fission in oriented terrylenediimide and quaterrylenediimide films
Singlet fission in organic semiconductors provides an important opportunity to study high-
spin states in electronically coupled chromophores. Photoexcitation of oriented, crystalline …
spin states in electronically coupled chromophores. Photoexcitation of oriented, crystalline …
Influence of core-twisted structure on singlet fission in perylenediimide film
J Zhou, H Liu, W Wang, T Li, Z Li, Z Liu, Y Chen… - … of Photochemistry and …, 2023 - Elsevier
To reveal the relationship between molecular packing and singlet fission (SF) property is
necessary for developing efficient SF materials, yet it remains unclear. Herein, we …
necessary for developing efficient SF materials, yet it remains unclear. Herein, we …
Singlet Fission Dynamics in the 5, 12-Bis (phenylethynyl) tetracene Thin Film
The singlet fission (SF) process is a promising route to overcome the Shockley and Quiesser
efficiency limit of organic solar cells and hence has attracted significant research interest in …
efficiency limit of organic solar cells and hence has attracted significant research interest in …