Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
Examining the relationship between coordination mode and reactivity of dinitrogen
RJ Burford, MD Fryzuk - Nature Reviews Chemistry, 2017 - nature.com
Molecular nitrogen (N2) is the most abundant gas in Earth's atmosphere, but its low reactivity
has hampered its use as a precursor to higher value nitrogen-containing compounds …
has hampered its use as a precursor to higher value nitrogen-containing compounds …
Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor
While recent spectroscopic studies have established the presence of an interstitial carbon
atom at the center of the iron–molybdenum cofactor (FeMoco) of MoFe-nitrogenase, its role …
atom at the center of the iron–molybdenum cofactor (FeMoco) of MoFe-nitrogenase, its role …
Binding of dinitrogen to an iron–sulfur–carbon site
Nitrogenases are the enzymes by which certain microorganisms convert atmospheric
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …
[HTML][HTML] Terminal Iron–Dinitrogen and Iron–Imide Complexes Supported by a Tris (phosphino) borane Ligand
Our currently limited understanding of the mechanism of biological dinitrogen fixation [1]–ie
the reduction of N2 to two equivalents of ammonia by addition of protons and electrons …
the reduction of N2 to two equivalents of ammonia by addition of protons and electrons …
Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron
The biological reduction of N2 to give NH3 may occur by one of two predominant pathways
in which nitrogenous N x H y intermediates, including hydrazine (N2H4), diazene (N2H2) …
in which nitrogenous N x H y intermediates, including hydrazine (N2H4), diazene (N2H2) …
Insight into the iron–molybdenum cofactor of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands
I Čorić, PL Holland - Journal of the American Chemical Society, 2016 - ACS Publications
Nitrogenase enzymes are used by microorganisms for converting atmospheric N2 to
ammonia, which provides an essential source of N atoms for higher organisms. The active …
ammonia, which provides an essential source of N atoms for higher organisms. The active …
Characterization of an FeN–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3
The ability of certain transition metals to mediate the reduction of N2 to NH3 has attracted
broad interest in the biological and inorganic chemistry communities. Early transition metals …
broad interest in the biological and inorganic chemistry communities. Early transition metals …
Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine
N Hazari - Chemical Society Reviews, 2010 - pubs.rsc.org
One of the most challenging problems in small molecule activation is the development of a
homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and …
homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and …
Iron–dinitrogen coordination chemistry: dinitrogen activation and reactivity
JL Crossland, DR Tyler - Coordination Chemistry Reviews, 2010 - Elsevier
Understanding the coordination of dinitrogen to iron is important for understanding
biological nitrogen fixation as well as for designing synthetic systems that are capable of …
biological nitrogen fixation as well as for designing synthetic systems that are capable of …