Recent Advances of Solid‐State NMR Spectroscopy for Microporous Materials

S Li, O Lafon, W Wang, Q Wang, X Wang… - Advanced …, 2020 - Wiley Online Library
Microporous materials have attracted a rapid growth of research interest in materials science
and the multidisciplinary area because of their wide applications in catalysis, separation, ion …

Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra

A Bavykina, A Cadiau, J Gascon - Coordination Chemistry Reviews, 2019 - Elsevier
The possibility of creating well controlled empty space into liquids is both, conceptually and,
from the application point of view, very attractive. Since James, Cooper and co-workers …

Selective adsorptive separation of cyclohexane over benzene using thienothiophene cages

Y Ding, LO Alimi, B Moosa, C Maaliki, J Jacquemin… - Chemical …, 2021 - pubs.rsc.org
The selective separation of benzene (Bz) and cyclohexane (Cy) is one of the most
challenging chemical separations in the petrochemical and oil industries. In this work, we …

Hyper-CEST NMR of metal organic polyhedral cages reveals hidden diastereomers with diverse guest exchange kinetics

J Jayapaul, S Komulainen, VV Zhivonitko… - Nature …, 2022 - nature.com
Guest capture and release are important properties of self-assembling nanostructures. Over
time, a significant fraction of guests might engage in short-lived states with different …

Decorated Traditional Zeolites with Subunits of Metal–Organic Frameworks for CH4/N2 Separation

Y Wu, D Yuan, D He, J Xing, S Zeng… - Angewandte Chemie …, 2019 - Wiley Online Library
Metal–organic frameworks (MOF) materials are promising materials for gas separation, but
their application still faces various challenges. A strategy is now reported for introducing …

129Xe NMR on Porous Materials: Basic Principles and Recent Applications

D Wisser, M Hartmann - Advanced Materials Interfaces, 2021 - Wiley Online Library
A large number of functional and catalytic materials exhibit porosity, often on different length
scales and with a hierarchical structure. The assessment of pore sizes, pore geometry, and …

NMR chemical shift of confined 129 Xe: coordination number, paramagnetic channels and molecular dynamics in a cryptophane-A biosensor

P Hilla, J Vaara - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Advances in hyperpolarisation and indirect detection have enabled the development of
xenon nuclear magnetic resonance (NMR) biosensors (XBSs) for molecule-selective …

Porous organic cage CC3: An effective promoter for methane hydrate formation for natural gas storage

S Denning, JM Lucero, AAA Majid… - The Journal of …, 2021 - ACS Publications
Herein, the synergistic effect of combining gas hydrates with a novel prototypical porous
organic cage, denoted as CC3 (microporous crystalline structure with diamondoid pores), for …

Porous organic cages CC3 and CC2 as adsorbents for the separation of carbon dioxide from nitrogen and hydrogen

K Krishnan, JM Crawford, PK Thallapally… - Industrial & …, 2022 - ACS Publications
The selective capture of carbon dioxide over nitrogen and hydrogen is of great industrial
interest in flue gas and hydrogen purification, respectively. Microporous adsorbents are …

Exploring cavities in Type II porous liquids with xenon

M Boventi, M Mauri, F Alexander, SL James… - Journal of Molecular …, 2023 - Elsevier
The porous topology of Type II Porous Liquids (PLs), prepared using Noria-OEt as an empty
molecular host dissolved in 15-crown-5 solvent, is investigated with 129 Xe NMR …