Mixed-metal metal–organic frameworks

S Abednatanzi, PG Derakhshandeh… - Chemical Society …, 2019 - pubs.rsc.org
Mixed-metal MOFs are metal–organic frameworks that contain at least 2 different metal ions
as nodes of their frameworks. They are prepared relatively easily by either a one-pot …

Stimuli-modulated metal oxidation states in photochromic MOFs

CR Martin, KC Park, GA Leith, J Yu… - Journal of the …, 2022 - ACS Publications
Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching
between two discrete linker photoisomers via an external stimulus was probed for the first …

Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects

F Afshariazar, A Morsali - Chemical Society Reviews, 2025 - pubs.rsc.org
Owing to increasing global demand for the development of multifunctional advanced
materials with various practical applications, great attention has been paid to metal–organic …

Cooperative and orthogonal switching in the solid state enabled by metal‐organic framework confinement leading to a thermo‐photochromic platform

GR Wilson, KC Park, GC Thaggard… - Angewandte …, 2023 - Wiley Online Library
Cooperative behavior and orthogonal responses of two classes of coordinatively integrated
photochromic molecules towards distinct external stimuli were demonstrated on the first …

Phase transitions and coexistence of magnetic and electric orders in the methylhydrazinium metal formate frameworks

M Mączka, A Gagor, M Ptak, W Paraguassu… - Chemistry of …, 2017 - ACS Publications
We report the synthesis of four perovskite-type metal formate frameworks,[CH3NH2NH2][M
(HCOO) 3](MHyM) with M= Mn, Mg, Fe, and Zn. These compounds exhibit two structural …

Decomposition process of carboxylate MOF HKUST-1 unveiled at the atomic scale level

M Todaro, G Buscarino, L Sciortino… - The Journal of …, 2016 - ACS Publications
HKUST-1 is a metal–organic framework (MOF) which plays a significant role in both
applicative and basic fields of research, thanks to its outstanding properties of adsorption …

Multifunctional Catalysis by a One-Dimensional Copper (II) Metal Organic Framework Containing Pre-existing Coordinatively Unsaturated Sites: Intermolecular C–N …

S Rasaily, D Sharma, S Pradhan, N Diyali… - Inorganic …, 2022 - ACS Publications
The coordinatively unsaturated sites (CUS) are vital in metal-centered catalysis. Metal–
organic frameworks (MOFs) provide a unique opportunity to generate and stabilize CUS due …

What lies beneath a metal–organic framework crystal structure? New design principles from unexpected behaviors

MD Allendorf, V Stavila, M Witman… - Journal of the …, 2021 - ACS Publications
The rational design principles established for metal–organic frameworks (MOFs) allow clear
structure–property relationships, fueling expansive growth for energy storage and …

Noncovalent dualism in perylene-diimide-based keggin anion complexes: theoretical and experimental studies

VG Popova, LV Kulik, RI Samoilova, DV Stass… - Inorganic …, 2023 - ACS Publications
We report the synthesis and comprehensive characterization of organic–inorganic hybrid
salts formed by bis-cationic N, N′-bis (2-(trimethylammonium) ethylene) perylene-3, 4, 9 …

Mixed-valent stellated cuboctahedral Cu (2, 4-Imdb)-MOF for trace water detection

SK Sachan, G Anantharaman - Inorganic Chemistry, 2022 - ACS Publications
Developing an economical and robust sensor using an earth-abundant metal-based metal–
organic framework (MOF) to detect trace water content rapidly is crucial for laboratories and …