Vibrational spectroscopy and dynamics of water
We present an overview of recent static and time-resolved vibrational spectroscopic studies
of liquid water from ambient conditions to the supercooled state, as well as of crystalline and …
of liquid water from ambient conditions to the supercooled state, as well as of crystalline and …
Molecular structure and modeling of water–air and ice–air interfaces monitored by sum-frequency generation
From a glass of water to glaciers in Antarctica, water–air and ice–air interfaces are abundant
on Earth. Molecular-level structure and dynamics at these interfaces are key for …
on Earth. Molecular-level structure and dynamics at these interfaces are key for …
Hydrogen bonding at the water surface revealed by isotopic dilution spectroscopy
IV Stiopkin, C Weeraman, PA Pieniazek, FY Shalhout… - Nature, 2011 - nature.com
The air–water interface is perhaps the most common liquid interface. It covers more than 70
per cent of the Earth's surface and strongly affects atmospheric, aerosol and environmental …
per cent of the Earth's surface and strongly affects atmospheric, aerosol and environmental …
Structure and dynamics of interfacial water studied by heterodyne-detected vibrational sum-frequency generation
S Nihonyanagi, JA Mondal… - Annual review of …, 2013 - annualreviews.org
Vibrational sum-frequency generation (VSFG) spectroscopy is a powerful tool to study
interfaces. Recently, multiplex heterodyne-detected VSFG (HD-VSFG) has been developed …
interfaces. Recently, multiplex heterodyne-detected VSFG (HD-VSFG) has been developed …
Phase-sensitive sum-frequency spectroscopy
YR Shen - Annual review of physical chemistry, 2013 - annualreviews.org
Phase-sensitive sum-frequency spectroscopy (SFS) allows the complete measurement of
the complex spectra of surface nonlinear response coefficients. Similar to linear …
the complex spectra of surface nonlinear response coefficients. Similar to linear …
Unified Molecular View of the Air/Water Interface Based on Experimental and Theoretical χ(2) Spectra of an Isotopically Diluted Water Surface
S Nihonyanagi, T Ishiyama, T Lee… - Journal of the …, 2011 - ACS Publications
The energetically unfavorable termination of the hydrogen-bonded network of water
molecules at the air/water interface causes molecular rearrangement to minimize the free …
molecules at the air/water interface causes molecular rearrangement to minimize the free …
Molecular Structure and Dynamics of Water at the Water–Air Interface Studied with Surface‐Specific Vibrational Spectroscopy
Water interfaces provide the platform for many important biological, chemical, and physical
processes. The water–air interface is the most common and simple aqueous interface and …
processes. The water–air interface is the most common and simple aqueous interface and …
Recent progress on sum-frequency spectroscopy
CS Tian, YR Shen - Surface Science Reports, 2014 - Elsevier
Second harmonic generation (SHG) and sum frequency spectroscopy (SFS) have provided
unique opportunities to probe surfaces and interfaces. They have found broad applications …
unique opportunities to probe surfaces and interfaces. They have found broad applications …
2D H-bond network as the topmost skin to the air–water interface
S Pezzotti, DR Galimberti… - The journal of physical …, 2017 - ACS Publications
We provide a detailed description of the structure of water at the interface with the air (liquid–
vapor LV interface) from state-of-the-art DFT-based molecular dynamics simulations. For the …
vapor LV interface) from state-of-the-art DFT-based molecular dynamics simulations. For the …
Toward ab initio molecular dynamics modeling for sum-frequency generation spectra; an efficient algorithm based on surface-specific velocity-velocity correlation …
Interfacial water structures have been studied intensively by probing the O–H stretch mode
of water molecules using sum-frequency generation (SFG) spectroscopy. This surface …
of water molecules using sum-frequency generation (SFG) spectroscopy. This surface …