Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

There are mechanistic dichotomies with regard to the formation, electronic structures and
reaction mechanisms of metal–oxygen intermediates, since these metal–oxygen species …

Catalytic oxidation reactions are pivotal transformations in living creatures and chemical
industries, in which metal-oxygen intermediates, including high-valent metal-oxo species …

Epoxidation of alkenes is a significant reaction in organic chemistry due to its opportunities
in producing compounds of biochemical interest. Catalytic epoxidation with first‐row …

There are many examples in bioinorganic chemistry, where metalloenzymes produce
different reaction products than analogous biomimetic model complexes despite them …

Treatment of (ArL) CoBr (ArL= 5-mesityl-1, 9-(2, 4, 6-Ph3C6H2) dipyrrin) with a
stoichiometric amount of 1-azido-4-(tert-butyl) benzene N3 (C6H4-pt Bu) furnished the …

The oxidation of aldehyde is one of the fundamental reactions in the biological system.
Various synthetic procedures and catalysts have been developed to convert aldehydes into …

The strong C–H bond activation of hydrocarbons is a difficult reaction in environmental and
biological chemistry. Herein, a high-valent manganese (IV)-hydroxo complex,[MnIV (CHDAP …

We report that Mn (III)-iodosylarene porphyrins,[MnIII (Porp)(sArIO)]+, are capable of
activating the C–H bonds of hydrocarbons, including unactivated alkanes such as …

Conspectus Metalloenzymes, which are proteins containing earth-abundant transition-metal
ions as cofactors in the active site, generate various metal–oxygen intermediates via …