Large-scale computations in chemistry: a bird's eye view of a vibrant field

AV Akimov, OV Prezhdo - Chemical reviews, 2015 - ACS Publications
1.1. The Meaning of “Large Scale” In general, the term “large scale” can have one of the
following five meanings in computational chemistry:(1) large size: power-law and …

Metal-organic complexes-towards promising organic thermoelectric materials

Y Sun, W Xu, C Di, D Zhu - Synthetic Metals, 2017 - Elsevier
Recent research progress has drawn the attention to thermoelectric (TE) property of Poly (M-
ett)(M= metal, ett= ethylenetetrathiolate), which provides the best performance of n-type …

Dichroic Palladium Dithiolate Coordination Polymers

AS Sergeenko, D Paripovic… - Crystal Growth & …, 2023 - ACS Publications
An isomorphous series of coordination polymers with the general formula M (H2O) 4 [Pd (iso-
maleonitriledithiolate) 2]· 2H2O (M= Mn, Co, Zn) was structurally characterized. They exhibit …

On the path to gold: Monoanionic Au bisdithiolate complexes with antimicrobial and antitumor activities

SA Sousa, JH Leitão, RAL Silva, D Belo… - Journal of Inorganic …, 2020 - Elsevier
The emergence of resistance to antimicrobial and anticancer drugs poses severe threats to
public health worldwide, highlighting the need for more efficient treatments. Here, four …

Spin-ladder behaviour in molecular materials

RAL Silva, M Almeida - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Spin-ladders are quantum magnetic systems at the crossroads between one and two
dimensions that have attracted increasing interest during the last decades due to unique …

Electronic engineering of a tetrathiafulvalene charge-transfer salt via reduced symmetry induced by combined substituents

Y Kiyota, IR Jeon, O Jeannin, M Beau… - Physical Chemistry …, 2019 - pubs.rsc.org
A 1: 1 metallic charge-transfer salt is obtained by cosublimation of (Z, E)-(SMe) 2Me2TTF
and TCNQ. X-ray diffraction studies confirm the formation of segregated stacks comprising …

Acceptor-donor-acceptor π-extended systems based on α-dithiophenetetrathiafulvalene (α-DT-TTF): Facile synthesis and photoconductivity studies

MFG Velho, A Paracana, J Serra, L Alcácer, J Avó… - Dyes and …, 2022 - Elsevier
Abstract π-Extended derivatives of the electron donor (D) α-dithiophenetetrathiafulvalene (α-
DT-TTF) were prepared for the first time. The compounds consisting of α-DT-TTF covalently …

Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z, E)-Me 2 I 2 TTF] …

O Jeannin, E Canadell, P Auban-Senzier… - Chemical …, 2016 - pubs.rsc.org
The Z and E isomers of the iodinated TTF derivative (Z, E)-Me2I2-TTF co-crystallize in a
mixed-valence salt with Br− anions, and are segregated into Z and E stacks, each of them …

Multi-Triplon Excitations of Hubbard Ladders with Site-Dependent Potentials

N Maeshima, K Hino - Journal of the Physical Society of Japan, 2024 - journals.jps.jp
We study low-lying spin-singlet excitations of two-leg Hubbard ladders with site-dependent
potentials. Using general formulas of the charge disproportionation induced by the site …

Analysis of self-consistent extended Hückel theory (SC-EHT): A new look at the old method

AV Akimov, OV Prezhdo - Journal of Mathematical Chemistry, 2015 - Springer
We present an extensive analysis of the self-consistent extended Hückel theory (SC-EHT)
and discuss the possibilities of constructing accurate and efficient semiempirical methods on …