The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …

This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …

We report the use of solution and solid-state 31P Nuclear Magnetic Resonance (NMR)
spectroscopy combined with Density Functional Theory calculations to benchmark the …

Phosphorus-containing molecules are ubiquitous in the world around us, and the synthetic
and industrial utilization of phosphorus has prospered for over a century. 1, 2 The industrial …

The synthesis and characterization of the complexes Mo [N (R) Ar] 3 (R= C (CD3) 2CH3, Ar=
3, 5-C6H3Me2),(μ-N2){Mo [N (R) Ar] 3} 2,(μ-15N2){Mo [N (R) Ar] 3} 2, NMo [N (R) Ar] 3 …

Recently there has been great interest in the reactivity of transition‐metal (TM) centers
towards white phosphorus (P4). This has ultimately been motivated by a desire to find TM …

Triamidoamine ligands [(RNCH2CH2) 3N] 3-in which R is a bulky substituent, can bind to a
variety of transition metals (or main group elements1) in oxidation states 3+ or higher. They …

Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …

Carbide complexes remain a rare class of molecules. Their paucity does not reflect
exceptional instability but is rather due to the generally narrow scope of synthetic …

Despite their potential relevance as molecular models for industrial and biological catalysis,
well-defined mononuclear iron carbide complexes are unknown, in part due to the limited …