Toolbox for distal C–H bond functionalizations in organic molecules
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
Metal-catalysed C–H bond activation and borylation
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …
received a remarkable level of attention as a popular reaction in the synthesis of …
Transition metal catalysis controlled by hydrogen bonding in the second coordination sphere
Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …
processes in academia and industry. The activity and selectivity of metal complexes are …
[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool
MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …
method that offers versatile synthetic transformation from organoboron compounds to …
Achieving site-selectivity for C–H activation processes based on distance and geometry: a carpenter's approach
The ability to differentiate between highly similar C–H bonds in a given molecule remains a
fundamental challenge in organic chemistry. In particular, the lack of sufficient steric and …
fundamental challenge in organic chemistry. In particular, the lack of sufficient steric and …
Arene diversification through distal C(sp2)−H functionalization
BACKGROUND Organic synthetic chemistry has facilitated the production of medicines,
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …
New horizons for catalysis disclosed by supramolecular chemistry
G Olivo, G Capocasa, D Del Giudice… - Chemical Society …, 2021 - pubs.rsc.org
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
Hydrogen-bond-acceptor ligands enable distal C(sp3)–H arylation of free alcohols
The functionalization of C–H bonds in organic molecules is one of the most direct
approaches for chemical synthesis. Recent advances in catalysis have allowed native …
approaches for chemical synthesis. Recent advances in catalysis have allowed native …