Catalysis in liquid organic hydrogen storage: recent advances, challenges, and perspectives

MS Salman, N Rambhujun, C Pratthana… - Industrial & …, 2022 - ACS Publications
With the renewed interest for hydrogen as an energy carrier, means to produce, but most
importantly store, transport, and distribute,“green” hydrogen over long distances has …

Understanding Methanol Synthesis on Inverse ZnO/CuOx/Cu Catalysts: Stability of CH3O Species and Dynamic Nature of the Surface

I Orozco, E Huang, M Mahapatra, J Kang… - The Journal of …, 2021 - ACS Publications
Inverse ZnO/Cu catalysts are key systems in the conversion of CO2, a common atmospheric
pollutant, into methanol, a high-value chemical and fuel. The chemistry of methanol and …

In Situ Studies of Methanol Decomposition Over Cu(111) and Cu2O/Cu(111): Effects of Reactant Pressure, Surface Morphology, and Hot Spots of Active Sites

I Orozco, E Huang, M Mahapatra, R Shi… - The Journal of …, 2020 - ACS Publications
The dissociative adsorption of methanol was investigated on Cu (111) and ultrathin Cu2O
films. We employed synchrotron-based Ambient Pressure X-ray Photoelectron Spectroscopy …

Redox-mediated reconstruction of copper during carbon monoxide oxidation

F Xu, K Mudiyanselage, AE Baber… - The Journal of …, 2014 - ACS Publications
Copper has excellent initial activity for the oxidation of CO, yet it rapidly deactivates under
reaction conditions. In an effort to obtain a full picture of the dynamic morphological and …

Accelerated Cu2O Reduction by Single Pt Atoms at the Metal-Oxide Interface

AC Schilling, K Groden, JP Simonovis, A Hunt… - ACS …, 2020 - ACS Publications
The reducibility of metal oxides, when they serve as the catalyst support or are the active
sites themselves, plays an important role in heterogeneous catalytic reactions. Here we …

Crystal-plane-dependent redox reaction on Cu surfaces

Y Li, H Chen, W Wang, W Huang, Y Ning, Q Liu, Y Cui… - Nano Research, 2020 - Springer
The dynamic redox process of surface oxide layers on metal surfaces is of great significance
for understanding the active phase in catalytic reactions. We studied the formation of surface …

In situ environmental TEM observation of two-stage shrinking of Cu 2 O islands on Cu (100) during methanol reduction

H Chi, MT Curnan, M Li, CM Andolina… - Physical Chemistry …, 2020 - pubs.rsc.org
The structural dynamics of Cu catalyst regeneration from Cu2O under methanol is poorly
understood. In situ Environmental TEM on Cu (100)-supported Cu2O islands reveals a …

Systematic study of adsorption and the reaction of methanol on three model catalysts: Cu (111), Zn–Cu (111), and Oxidized Zn–Cu (111)

T Koitaya, Y Shiozawa, Y Yoshikura… - The Journal of …, 2017 - ACS Publications
The adsorption and reaction of methanol on Zn-modified Cu (111) surfaces were
investigated by synchrotron-radiation X-ray photoelectron spectroscopy (XPS) and …

Surface-templated assembly of molecular methanol on the thin film “29” Cu (111) surface oxide

AJ Therrien, AJR Hensley, RT Hannagan… - The Journal of …, 2019 - ACS Publications
Identifying and characterizing the atomic-scale interaction of methanol with oxidized Cu
surfaces is of fundamental relevance to industrial reactions, such as methanol steam …

Desorption trends of small alcohols and the disruption of intermolecular interactions at defect sites on Au (111)

EM Maxwell, LA Garber, CJ Rogers… - Physical Chemistry …, 2022 - pubs.rsc.org
Gold-based catalysts have received tremendous attention as supports and nanoparticles for
heterogeneous catalysis, in part due to the ability of nanoscale Au to catalyze reactions at …