Porous metal–organic frameworks for hydrogen storage

D Zhao, X Wang, L Yue, Y He, B Chen - Chemical Communications, 2022 - pubs.rsc.org
The high gravimetric energy density and environmental benefits place hydrogen as a
promising alternative to the widely used fossil fuels, which is however impeded by the lack of …

Defects on carbons for electrocatalytic oxygen reduction

X Yan, Y Jia, X Yao - Chemical Society Reviews, 2018 - pubs.rsc.org
The exploration of highly active and durable cathodic oxygen reduction reaction (ORR)
catalysts with economical production costs is still the bottleneck to realize the large-scale …

Efficient purification of ethene by an ethane-trapping metal-organic framework

PQ Liao, WX Zhang, JP Zhang, XM Chen - Nature communications, 2015 - nature.com
Abstract Separating ethene (C2H4) from ethane (C2H6) is of paramount importance and
difficulty. Here we show that C2H4 can be efficiently purified by trapping the inert C2H6 in a …

Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal …

TR Cook, YR Zheng, PJ Stang - Chemical reviews, 2013 - ACS Publications
In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …

Review on metal–organic framework classification, synthetic approaches, and influencing factors: applications in energy, drug delivery, and wastewater treatment

VF Yusuf, NI Malek, SK Kailasa - ACS omega, 2022 - ACS Publications
Metal ions or clusters that have been bonded with organic linkers to create one-or more-
dimensional structures are referred to as metal–organic frameworks (MOFs). Reticular …

Quantum-chemical characterization of the properties and reactivities of metal–organic frameworks

SO Odoh, CJ Cramer, DG Truhlar, L Gagliardi - Chemical reviews, 2015 - ACS Publications
The present review is concerned with quantum mechanical electronic structure calculations
on metal− organic frameworks (MOFs) to elucidate their properties and functionalities. There …

Electronic effects of ligand substitution on metal–organic framework photocatalysts: the case study of UiO-66

L Shen, R Liang, M Luo, F Jing, L Wu - Physical chemistry chemical …, 2015 - pubs.rsc.org
UiO-66-X (X= H, NH2, NO2, Br) have been successfully synthesized and tested for their
photocatalytic activity in water treatment. Results show that electronic effect of the ligand …

Activation of metal–organic framework materials

JE Mondloch, O Karagiaridi, OK Farha, JT Hupp - CrystEngComm, 2013 - pubs.rsc.org
Crystalline metal–organic frameworks (MOFs) have emerged as a highly desirable class of
solid-state materials. Some of their most attractive features include exceptionally high …

Ethane selective IRMOF-8 and its significance in ethane–ethylene separation by adsorption

J Pires, ML Pinto, VK Saini - ACS applied materials & interfaces, 2014 - ACS Publications
The separation of ethylene from ethane is one of the most energy-intensive single
distillations practiced. This separation could be alternatively made by an adsorption process …

Metal‐Organic Framework (MOF) Morphology Control by Design

K Suresh, AP Kalenak, A Sotuyo… - Chemistry–A European …, 2022 - Wiley Online Library
Exerting morphological control over metal‐organic frameworks (MOFs) is critical for
determining their catalytic performance and to optimize their packing behavior in areas from …