Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

V Aomchad, À Cristòfol, F Della Monica, B Limburg… - Green …, 2021 - pubs.rsc.org
Cyclic organic carbonates are among the most widely studied targets in the nonreductive
conversion of carbon dioxide using oxiranes as the common reaction partners. Apart from …

Aminolysis of cyclic-carbonate vegetable oils as a non-isocyanate route for the synthesis of polyurethane: A kinetic and thermal study

WY Pérez-Sena, X Cai, N Kebir… - Chemical Engineering …, 2018 - Elsevier
Production of polyurethane is increasing since the recent years. Nevertheless, this
production uses hazardous chemicals, which is isocyanate. Academy has put a lot of effort to …

Use of semibatch reactor technology for the investigation of reaction mechanism and kinetics: Heterogeneously catalyzed epoxidation of fatty acid esters

WY Perez-Sena, J Wärnå, K Eränen, P Tolvanen… - Chemical Engineering …, 2021 - Elsevier
Heterogeneously catalyzed epoxidation of vegetable oils by hydrogen peroxide represents
a greener route for the production of epoxides and a thermally safer reaction route …

Optimizing carbonation reaction parameters of calcium carbide slag in acidic/alkaline environment enhancing CO2 mineralization efficiency

Z Pan, L Chen, C Cao, F Zhang, H Zhang… - Chemical Engineering …, 2024 - Elsevier
Carbide slag (CS) is a typical alkaline solid waste with Ca (OH) 2 as its main component,
exhibiting a high capacity for CO 2 mineralization. Currently, the methods for CS …

Boric acid as a hydrogen bond donor with TBAB catalyze the cycloaddition of CO2 to internal bio-epoxides under solvent-free conditions

L Long, Y Liu, W Liu - Molecular Catalysis, 2023 - Elsevier
The cycloaddition of CO 2 with epoxides is regarded as one of the most efficient methods to
synthesize cyclic carbonate because of the 100% atom utilization. Therefore, it is necessary …

Thermal safety assessment through the concept of structure–reactivity: application to vegetable oil valorization

S Leveneur - Organic Process Research & Development, 2017 - ACS Publications
The concept of linear free-energy relationships, and more particularly the Taft equation, was
extended to a multiphase system with several reactions and reaction centers: the …

[HTML][HTML] Carbonation of epoxidized soybean oil in supercritical CO2 assisted by imidazole-based organocatalysts

J Catalá, MP Caballero, F de la Cruz-Martínez… - Journal of CO2 …, 2022 - Elsevier
Production of cyclic carbonates from epoxidized vegetable oils allows to introduce CO 2 into
the molecular structure of renewable and highly functional resources, obtaining high added …

Parameters affecting thermal risk through a kinetic model under adiabatic condition: Application to liquid-liquid reaction system

S Leveneur, M Pinchard, A Rimbault, MS Shadloo… - Thermochimica …, 2018 - Elsevier
Risk of thermal runaway for epoxidation is not negligible and should be analyzed and
assessed. In industry, epoxidation of vegetable oils is carried out by the oxidation of …

Influence of gas-liquid mass transfer on kinetic modeling: Carbonation of epoxidized vegetable oils

X Cai, JL Zheng, J Wärnå, T Salmi, B Taouk… - Chemical Engineering …, 2017 - Elsevier
Fossil depletion and global warming have pushed industrial and academic communities to
rethink the present way of consumption by diminishing waste and by using renewable raw …

Investigation of the physicochemical properties for vegetable oils and their epoxidized and carbonated derivatives

X Cai, K Ait Aissa, L Estel… - Journal of Chemical & …, 2018 - ACS Publications
Vegetable oils are more and more used in industry for the production of biodiesel,
biolubricant, or polymer. In this context, production of polyurethane by nonisocyanate routes …