Mechanisms of stereodirecting participation and ester migration from near and far in glycosylation and related reactions

AA Hettikankanamalage, R Lassfolk, FS Ekholm… - Chemical …, 2020 - ACS Publications
This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

Automated chemical oligosaccharide synthesis: novel approach to traditional challenges

M Panza, SG Pistorio, KJ Stine… - Chemical reviews, 2018 - ACS Publications
Advances in carbohydrate chemistry have certainly made common oligosaccharides much
more accessible. However, many current methods still rely heavily upon specialized …

The Experimental Evidence in Support of Glycosylation Mechanisms at the SN1–SN2 Interface

PO Adero, H Amarasekara, P Wen, L Bohé… - Chemical …, 2018 - ACS Publications
A critical review of the state-of-the-art evidence in support of the mechanisms of
glycosylation reactions is provided. Factors affecting the stability of putative oxocarbenium …

Stereocontrolled 1, 2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry

SS Nigudkar, AV Demchenko - Chemical science, 2015 - pubs.rsc.org
Recent developments in stereoselective 1, 2-cis glycosylation that have emerged during the
past decade are surveyed herein. For detailed coverage of the previous achievements in the …

Challenges in the development of organic and hybrid molecular systems

VP Ananikov, KI Galkin, MP Egorov… - Mendeleev …, 2016 - Elsevier
The rapid development of organic chemistry and catalysis has provided outstanding
chemical tools to build complex molecular architectures that were never possible before. In …

[HTML][HTML] A propos of glycosyl cations and the mechanism of chemical glycosylation

L Bohé, D Crich - Comptes Rendus Chimie, 2011 - Elsevier
A critical overview of the current state of the art regarding the mechanism of chemical
glycosylation reactions is presented. Particular emphasis is placed on the glycosyl …

Pyranoside‐into‐Furanoside Rearrangement: New Reaction in Carbohydrate Chemistry and Its Application in Oligosaccharide Synthesis

VB Krylov, DA Argunov, DZ Vinnitskiy… - … A European Journal, 2014 - Wiley Online Library
Great interest in natural furanoside‐containing compounds has challenged the development
of preparative methods for their synthesis. Herein a novel reaction in carbohydrate …

Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: remote protecting group effects and temperature dependency

J Kalikanda, Z Li - The Journal of Organic Chemistry, 2011 - ACS Publications
The stereoselectivity of glycosylation reactions is affected by many factors. Synthesis of 1, 2-
cis glycosidic linkages (such as α linkages in glucose and galactose like monosaccharides) …

[HTML][HTML] Novel protecting groups in carbohydrate chemistry

JDC Codee, A Ali, HS Overkleeft… - Comptes Rendus …, 2011 - Elsevier
Novel protecting groups in carbohydrate chemistry - ScienceDirect Skip to main contentSkip to
article Elsevier logo Journals & Books Search RegisterSign in View PDF Download full issue …

Chemical synthesis and application of biotinylated oligo-α-(1→ 3)-D-glucosides to study the antibody and cytokine response against the cell wall α-(1→ 3)-D-glucan of …

BS Komarova, SSW Wong, MV Orekhova… - The Journal of …, 2018 - ACS Publications
Biotinylated hepta-, nona-and undeca-α-(1→ 3)-d-glucosides representing long
oligosaccharides of α-(1→ 3)-d-glucan, one of the major components of the cell walls of the …