The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Rational control of the self-assembly of large structures is one of the key challenges in
chemistry,,,,,,,,, and is believed to become increasingly difficult and ultimately impossible as …

Self-assembly is invaluable in the construction of giant molecular structures via a bottom-up
approach. Although living organisms naturally make the most use of self-assembly and …

Iridium (III) complexes exhibit remarkable photophysical properties such as high
photoluminescence quantum yields, wide color tunability and high chemical stability. They …

Due to the existing challenges in the synthesis of covalently linked large organic cages, the
potential benefits of such gigantic structures have been less explored, comparatively. Here …

The tunable growth of metal–organic materials has implications for engineering particles
and surfaces for diverse applications. Specifically, controlling the self‐assembly of metal …

The synthesis of multivariate metal–organic frameworks (MOFs) is a well-known method for
increasing the complexity of porous frameworks. In these materials, the structural differences …

Two new structural motifs within the class of heteroleptic PdnAnBn assemblies, namely syn‐
cis‐Pd3A3B3 bowls and bowl‐(syn) or saddle‐(anti) shaped cis‐Pd4A4B4 rings are …

Discovering novel families of molecular polyhedra through graph theory has attracted
increasing interest. Nevertheless, the design principles of molecular polyhedra based on …

We report three self‐assembled iron complexes that comprised an anti‐parallel open form (o‐
Lanti), a parallel open form (o‐Lsyn), and a closed form (c‐L) of diarylethene conformers …