Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …

The oxidative metalation method, involving the interaction of free‐base meso‐triarylcorroles
and W (CO) 6 in refluxing decalin, led to a set of three tungsten (VI) biscorroles, the first …

Extensive DFT calculations with several exchange–correlation functionals indicate that
molybdenum-dichlorido Viking helmet corroles are noninnocent with significant MoIV …

The homoleptic sandwich compounds–Mo and W biscorroles–have afforded a novel
platform for experimental studies of relativistic effects. A 200 mV difference in reduction …

Chemically inert oxidometal (V) corrols of molybdenum and rhenium undergo clean ligand‐
exchange reactions upon the action of SiCl4. The resulting dichlorido complexes show …

Reaction of the free base corrole (Mes2 (p-OMePh) corrole) H3 with tantalum trialkyl
precursors TaMe3Cl2 and TaBn3NtBu resulted in the formation of the tantalum dichloride (1) …

We report the synthesis of high-valent molybdenum (VI) bis-imido complexes 1–4 with
dipyrromethene (DPM) supporting ligands of the general formula (DPMR) Mo (NR′) 2Cl (R …

A π‐extended, diaza‐triphenylene embedded, mono‐anionic corrole analogue and its NiII
complex were synthesized from a diaza‐triphenylene precursor, which was obtained from a …