The aryl C-glycoside structure is, among the plenty of biologically active natural products,
one of the distinct motifs embedded. Because of the potential bioactivity as well as the …

Photoredox reactions of quinones are reviewed, that enable C− H bond oxidation at the
vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under …

A concise and highly enantioselective route has been developed for the synthesis of
angucyclinone-type natural products. Utilizing this strategy, total syntheses of five natural …

The structurally unique polyketide mumbaistatin is the strongest naturally occurring inhibitor
of glucose‐6‐phosphate translocase‐1 (G6P‐T1), which is a promising target for drugs …

A total synthesis of the cembranoid (+)‐sarcophytin is presented, featuring a Diels–Alder
cycloaddition of an enone as the dienophile with an ester‐derived dienoate. The study …

Stereospermum fimbriatum or locally known as “Chicha” is traditionally used for itchy skin,
earache, stomachache and postpartum treatments. This study was designed to evaluate the …

A review with 1663 references to transition-metal catalyzed or mediated reactions and
functional group preparations.

Convergent enantioselective syntheses of angucyclinone‐type natural products rubiginones
A2 (2) and C2 (1) and their 11‐methoxy regioisomers 3 a and 3 b have been achieved by …

An efficient four-step route to the tetracyclic aminoquinone moiety of marmycin A that
proceeds in 41% overall yield from 5-nitronaphthoquinone and 5-methyl-1-vinylcyclohexene …

The regioselectivities of several Diels− Alder reactions utilized en route to bisanthraquinone
antibiotic BE-43472B are examined using density functional theory calculations. These …