Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

In this review, selected recent advances in the preparation and reactivity of aziridines using
modern synthetic approaches are highlighted, while comparing these new strategies with …

Although they offer great potentials, the high reactivity and diverse pathways of radical
chemistry pose difficult problems for applications in organic synthesis. In addition to the …

Recent advances in transition metal-catalyzed C–H bond functionalization have profoundly
impacted synthetic strategy. Since organic substrates typically contain several chemically …

Herein, visible‐light‐driven iron‐catalyzed nitrene transfer reactions with dioxazolones for
intermolecular C (sp3)‐N, N= S, and N= P bond formation are described. These reactions …

An efficient method for intermolecular branch-selective allylic C–H amidation has been
accomplished via Ir (III) catalysis. The reaction proceeds through initial allylic C–H activation …

C–H functionalization is a very active research field that has attracted the interest of
scientists from many disciplines. This Outlook describes the collaborative efforts within the …

C 4-Symmetrical dirhodium (II) tetracarboxylates are highly efficient catalysts for the
asymmetric intermolecular aziridination of substituted alkenes with sulfamates. The reaction …

Conspectus Carbon–nitrogen (C–N) bonds are ubiquitous in pharmaceuticals,
agrochemicals, diverse bioactive natural products, and ligands for transition metal catalysts …

Direct conversion of hydrocarbons into amines represents an important and atom-economic
goal in chemistry for decades. However, intermolecular cross-coupling of terminal alkenes …