Enantiomerically pure tertiary thiols provide a major synthetic challenge, and despite the
importance of chiral sulfur-containing compounds in biological and medicinal chemistry …

In 1980 sulfamic acid and its N-substituted derivatives were reviewed in Chemical Reviews,
1 effectively updating an earlier 1940 review 2 also in Chemical Reviews. In 1991 the …

We report here an unprecedented and highly enantioselective palladium‐catalyzed allylic
alkylation applied to 4‐substituted isoxazolidin‐5‐ones. Ultimately, the process provides a …

An atom-economic organocatalytic asymmetric Michael reaction of α, β, β-trisubstituted
olefins has been successfully developed. The reaction exhibits excellent enantioselectivities …

When combined with an appropriate nucleophilic component, 1, 2-and 1, 3-cyclic
sulfamidates function as versatile precursors to a range of substituted and enantiopure …

An unprecedented enantioselective α‐functionalization of C4‐substituted N‐alkoxycarbonyl
isoxazolidin‐5‐ones, readily available platforms from Meldrum's acid derivatives, by N …

Thioacetates as precursors of thiols are interesting starting points for synthesizing other
organosulfur compounds. Herein, we propose a simple, efficient and fast method to obtain …

The asymmetric synthesis of α‐heterofunctionalized α‐and β‐amino acid derivatives has
been a heavily investigated topic over the last years, benefiting from the development of …

Stereocontrolled intramolecular aziridination of the glycal‐derived sulfamates offers a highly
efficient strategy to divergently prepare aminoglycosides. Rhodium‐catalyzed nitrogen‐atom …

Lantibiotics such as nisin are active against most Gram-positive bacteria and constitute an
important class of antibacterial agents. These ribosomally synthesized peptides contain …