Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Confining enzymes in porous organic frameworks: from synthetic strategy and characterization to healthcare applications

S Huang, G Chen, G Ouyang - Chemical Society Reviews, 2022 - pubs.rsc.org
Enzymes are a class of natural catalysts with high efficiency, specificity, and selectivity
unmatched by their synthetic counterparts and dictate a myriad of reactions that constitute …

Metal–organic framework-based enzyme biocomposites

W Liang, P Wied, F Carraro, CJ Sumby… - Chemical …, 2021 - ACS Publications
Because of their efficiency, selectivity, and environmental sustainability, there are significant
opportunities for enzymes in chemical synthesis and biotechnology. However, as the three …

Recent advances in enzyme immobilization based on novel porous framework materials and its applications in biosensing

Y Feng, Y Xu, S Liu, D Wu, Z Su, G Chen, J Liu… - Coordination Chemistry …, 2022 - Elsevier
Enzyme immobilization in nano-space to maintain or even enhance their activity and stability
is generally challenging. In recent years, metal–organic frameworks (MOFs), covalent …

Hydrogen-bonded organic framework biomimetic entrapment allowing non-native biocatalytic activity in enzyme

G Chen, L Tong, S Huang, S Huang, F Zhu… - Nature …, 2022 - nature.com
Nature programs the structural folding of an enzyme that allows its on-demand
biofunctionality; however, it is still a long-standing challenge to manually modulate an …

Hierarchically encapsulating enzymes with multi-shelled metal-organic frameworks for tandem biocatalytic reactions

T Man, C Xu, XY Liu, D Li, CK Tsung, H Pei… - Nature …, 2022 - nature.com
Biocatalytic transformations in living organisms, such as multi-enzyme catalytic cascades,
proceed in different cellular membrane-compartmentalized organelles with high efficiency …

Nanostructured materials for photocatalysis

C Xu, PR Anusuyadevi, C Aymonier, R Luque… - Chemical Society …, 2019 - pubs.rsc.org
Photocatalysis is a green technology which converts abundantly available photonic energy
into useful chemical energy. With a rapid rise of flow photoreactors in the last decade, the …

Green and scalable fabrication of high‐performance biocatalysts using covalent organic frameworks as enzyme carriers

Y Zheng, S Zhang, J Guo, R Shi, J Yu… - Angewandte Chemie …, 2022 - Wiley Online Library
Enzyme immobilization is essential to the commercial viability of various critical large‐scale
biocatalytic processes. However, challenges remain for the immobilization systems, such as …

Pomegranate-bionic encapsulating horseradish peroxidase using dopamine flexible scaffold-coated multishell porous ZIF-8 to enhance immunochromatographic …

M Song, J Xing, H Cai, X Gao, C Li, C Liu, X Li, X Fu… - AcS Nano, 2023 - ACS Publications
Nanoparticle-natural enzyme complexes are receiving increasing attention as the promising
signal reporters for colorimetric lateral flow immunoassay (LFIA). Nonetheless, it remains a …

“Armor‐Plating” enzymes with metal–organic frameworks (MOFs)

S Huang, X Kou, J Shen, G Chen… - Angewandte Chemie …, 2020 - Wiley Online Library
Cell‐free enzymatic catalysis (CFEC) is an emerging biotechnology that enable the
biological transformations in complex natural networks to be imitated. This biomimetic …