Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

[HTML][HTML] Single-atom catalysts: from design to application

N Cheng, L Zhang, K Doyle-Davis, X Sun - Electrochemical Energy …, 2019 - Springer
Single-atom catalysis is a powerful and attractive technique with exceptional performance,
drastic cost reduction and notable catalytic activity and selectivity. In single-atom catalysis …

Single-atom alloys as a reductionist approach to the rational design of heterogeneous catalysts

G Giannakakis… - Accounts of chemical …, 2018 - ACS Publications
Conspectus Heterogeneous catalysts are workhorses in the industrial production of most
commodity and specialty chemicals, and have widespread energy and environmental …

Tackling CO poisoning with single-atom alloy catalysts

J Liu, FR Lucci, M Yang, S Lee… - Journal of the …, 2016 - ACS Publications
Platinum catalysts are extensively used in the chemical industry and as electrocatalysts in
fuel cells. Pt is notorious for its sensitivity to poisoning by strong CO adsorption. Here we …

Water‐Enhanced Synthesis of Higher Alcohols from CO2 Hydrogenation over a Pt/Co3O4 Catalyst under Milder Conditions

Z He, Q Qian, J Ma, Q Meng, H Zhou… - Angewandte Chemie …, 2016 - Wiley Online Library
The effect of water on CO2 hydrogenation to produce higher alcohols (C2–C4) was studied.
Pt/Co3O4, which had not been used previously for this reaction, was applied as the …

NiCu single atom alloys catalyze the CH bond activation in the selective non-oxidative ethanol dehydrogenation reaction

J Shan, J Liu, M Li, S Lustig, S Lee… - Applied Catalysis B …, 2018 - Elsevier
NiCu single atom alloy (SAA) nanoparticles supported on silica are reported to catalyze the
non-oxidative dehydrogenation of ethanol, selectively to acetaldehyde and hydrogen …

Recent progress in single-atom alloys: Synthesis, properties, and applications in environmental catalysis

Z Xu, Z Ao, M Yang, S Wang - Journal of Hazardous Materials, 2022 - Elsevier
Heterogeneous catalysts have made outstanding advancements in pollutants elimination as
well as energy and materials production over the past decades. Single-atom alloys (SAAs) …

[HTML][HTML] Carbon monoxide poisoning resistance and structural stability of single atom alloys

MT Darby, ECH Sykes, A Michaelides, M Stamatakis - Topics in catalysis, 2018 - Springer
Platinum group metals (PGMs) serve as highly active catalysts in a variety of heterogeneous
chemical processes. Unfortunately, their high activity is accompanied by a high affinity for …

Effect of collective dynamics and anharmonicity on entropy in heterogenous catalysis: Building the case for advanced molecular simulations

G Collinge, SF Yuk, MT Nguyen, MS Lee… - ACS …, 2020 - ACS Publications
We present a perspective on the computational determination of entropy and its effects and
consequences on heterogeneous catalysis. Special attention is paid to the role of …