This review is an extensive update to the comprehensive review on controlled/living radical
polymerization (CLRP) in dispersed systems published in 2008. 1 A note on nomenclature …

The dialkyldiazene or azo-compound initiators, which include azonitriles such as azobis
(isobutyronitrile)(AIBN), are one of the most important classes of initiator being widely used …

A biorenewable polymer is synthesized via a green process using the RAFT principle for the
first time in supercritical CO2 at 300 bar and 80° C. α‐Methylene‐γ‐butyrolactone polymers …

Solution polymerized styrene-butadiene rubber (SSBR) and SSBR with tert-
Butylchlorodiphenylsilane (TBCSi, large-volume functional groups) at the two ends of …

The RAFT polymerization of styrene in a solvent consisting of a water/alcohol mixture with
different water contents is performed and the solvent effects on polymerization kinetics …

The development of cleaner, more environmentally friendly processes in polymerization
technology is crucial due to the prevalent use of volatile organic solvents (VOCs), which are …

The kinetics of nitroxide-mediated dispersion copolymerization with crosslinking of styrene
(STY) and divinylbenzene (DVB) in supercritical carbon dioxide (scCO2) is addressed …

TIPNO (2, 2, 5-trimethyl-4-phenyl-3-azahexane-3-nitroxide)-alkoxyamine was found to give
reasonably controlled/living nitroxide-mediated (NMP) precipitation polymerizations of …

The kinetic modeling of reversible addition–fragmentation chain transfer (RAFT) dispersion
homopolymerization of vinyl monomers in supercritical carbon dioxide is addressed. The …

The use of sequential Bayesian methodology for model discrimination purposes in
reversible addition‐fragmentation transfer (RAFT) polymerization is analyzed and discussed …