Spin crossover nanomaterials: from fundamental concepts to devices

G Molnár, S Rat, L Salmon, W Nicolazzi… - Advanced …, 2018 - Wiley Online Library
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Spin‐Crossover Grafted Monolayer of a Co (II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups

V García‐López, N Giaconi, L Poggini… - Advanced Functional …, 2023 - Wiley Online Library
The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

[HTML][HTML] Light-induced spin crossover—Solution and solid-state processes

G Chastanet, M Lorenc, R Bertoni… - Comptes Rendus …, 2018 - Elsevier
This article overviews the different light-induced spin-crossover processes that are induced
using ligand photoreaction, photothermal effects, or optical absorption of the center metallic …

[HTML][HTML] Thermodynamical aspects of the spin crossover phenomenon

W Nicolazzi, A Bousseksou - Comptes Rendus Chimie, 2018 - Elsevier
Fundamental aspects of spin crossover (SCO) mechanisms are reviewed through
considerations of ligand/crystal field theory, thermodynamics, and modeling of the …

Complete set of elastic moduli of a spin-crossover solid: Spin-state dependence and mechanical actuation

M Mikolasek, MD Manrique-Juarez… - Journal of the …, 2018 - ACS Publications
Molecular spin crossover complexes are promising candidates for mechanical actuation
purposes. The relationships between their crystal structure and mechanical properties …

Coupling mechanical and electrical properties in spin crossover polymer composites

S Rat, M Piedrahita‐Bello, L Salmon… - Advanced …, 2018 - Wiley Online Library
Spin crossover particles of formula [Fe {(Htrz) 2 (trz)} 0.9 (NH2‐trz) 0.3](BF4) 1.1 and
average size of 20 nm±8 nm are homogeneously dispersed in poly (vinylidene fluoride‐co …

A Bistable Microelectromechanical System Actuated by Spin‐Crossover Molecules

MD Manrique‐Juarez, F Mathieu… - Angewandte …, 2017 - Wiley Online Library
We report on a bistable MEMS device actuated by spin‐crossover molecules. The device
consists of a freestanding silicon microcantilever with an integrated piezoresistive detection …

Control of the speed of a light-induced spin transition through mesoscale core–shell architecture

AC Felts, A Slimani, JM Cain, MJ Andrus… - Journal of the …, 2018 - ACS Publications
The rate of the light-induced spin transition in a coordination polymer network solid
dramatically increases when included as the core in mesoscale core–shell particles. A …

Photo‐thermal switching of individual plasmonically activated spin crossover nanoparticle imaged by ultrafast transmission electron microscopy

Y Hu, M Picher, NM Tran, M Palluel… - Advanced …, 2021 - Wiley Online Library
Spin crossover (SCO) is a promising switching phenomenon when implemented in
electronic devices as molecules, thin films or nanoparticles. Among the properties …