Polymer characterization by size-exclusion chromatography with multi-angle light scattering (SEC-MALS): a tutorial review

JB Matson, AQ Steele, JD Mase, MD Schulz - Polymer Chemistry, 2024 - pubs.rsc.org
This tutorial review presents the theory and application of SEC-MALS with minimal
equations and a focus on synthetic polymer characterization, serving as an entry point for …

Tricyclononenes and tricyclononadienes as efficient monomers for controlled ROMP: understanding structure–propagation rate relationships and enabling facile post …

LJ Kilgallon, TP McFadden, MS Sigman… - Chemical Science, 2024 - pubs.rsc.org
Grubbs 3rd-generation (G3) pre-catalyst-initiated ring-opening metathesis polymerization
(ROMP) remains an indispensable tool in the polymer chemist's toolbox. Tricyclononenes …

Influence of the Norbornene Anchor Group in Ru-Mediated Ring-Opening Metathesis Polymerization: Synthesis of Linear Polymers

SJ Scannelli, A Paripati, JR Weaver, C Vu… - …, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) mediated by Grubbs' first-generation
catalyst [G1,(PCy3) 2 (Cl) 2RuCHPh] and Grubbs' third-generation catalyst [G3,(H2IMes)(Cl) …

Ring-opening metathesis polymerization of norbornene–benzoladderene (macro) monomers

SJ Scannelli, M Alaboalirat, D Troya, JB Matson - Polymer Chemistry, 2023 - pubs.rsc.org
Norbornene-based monomers are common starting points in ring-opening metathesis
polymerization (ROMP) due to their high ring strain, and recent reports highlight how the …

Ring‐opening metathesis polymerization for synthesizing molecular bottlebrushes via the grafting‐through strategy

W Hou, X Yin, Y Zhou, Y Shi… - Journal of Polymer …, 2024 - Wiley Online Library
Molecular bottlebrush (MBB) has been considered as an important type of unimolecular
nanomaterial for widespread applications ranging from energy to biomedicine, due to its …

Solution Structure and Scaling Laws of Cylindrical and Tapered Bottlebrush Polymers

M Alaboalirat, SJ Scannelli, H Rahmaninejad… - …, 2023 - ACS Publications
Bottlebrush polymers are a unique class of macromolecular architectures with a plethora of
potential industrial and pharmaceutical applications that critically depend on the bottlebrush …

A general synthesis of cyclic bottlebrush polymers with enhanced mechanical properties via graft-through ring expansion metathesis polymerization

MJ Elardo, AM Levenson, APK Vasconcelos… - Chemical …, 2024 - pubs.rsc.org
Bottlebrush polymers represent an important class of macromolecular architectures, with
applications ranging from drug delivery to organic electronics. While there is an abundance …

Carbon Dioxide-Derived Poly (Propylene Carbonate) Bottlebrush Polymers: Synthesis, Viscoelastic Properties, and Degradation

DB Schwarz, KA Cavicchi, JM Eagan - Macromolecules, 2024 - ACS Publications
Bottlebrush poly (propylene carbonate)(PPC) was synthesized with defined molecular
dimensions in order to understand their relationship to viscoelastic properties. Chain …

Marriage of Organic and Grubbs Catalysts for Tandem Synthesis of Bottlebrush Polyesters

Y Huang, C Zhao, B Zhang, H Li, J Zhao - ACS Macro Letters, 2023 - ACS Publications
Bottlebrush polymers (BBPs) have gained wide attention for their special characters, such as
rigid main/side chains, stemming from the exceedingly high graft density. This study aims to …

Tricyclononenes and Tricyclononadienes as Efficient Monomers for ROMP: Understanding Structure–Propagation Rate Relationships and Enabling Facile Post …

L Kilgallon, T McFadden, M Sigman, J Johnson - 2024 - chemrxiv.org
Grubbs 3rd-generation (G3) pre-catalyst-initiated ring-opening metathesis polymerization
(ROMP) remains an indispensable tool in the polymer chemist's toolbox. Tricyclononenes …