Redox-active ligands in catalysis - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C2CS35228A
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C2CS35228A …

High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

The capture of carbon-centered radicals at a nickel (II) center is commonly featured in recent
cross-coupling and metallaphotoredox catalytic reactions. Despite its widespread …

The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

A sterically accessible tert-butyl-substituted dipyrrinato di-iron (II) complex [(t BuL) FeCl] 2
possessing two bridging chloride atoms was synthesized from the previously reported …

Nickel complexes have been widely employed as catalysts in C–C and C–heteroatom bond
formation reactions. In addition to Ni (0) and Ni (II) intermediates, several Ni-catalyzed …

The formal hydroamination/hydroamidation utilizing metal hydride is an appealing synthetic
tool for the construction of valuable nitrogen-containing compounds from unsaturated …

Metallonitrenes (M–N) are complexes with a subvalent atomic nitrogen ligand that have
been proposed as key reactive intermediates in nitrogen atom transfer reactions. However …

The trityl-substituted bisoxazoline (TrHBOX) was prepared as a chiral analogue to a
previously reported nickel dipyrrin system capable of ring-closing amination catalysis …

A nickel‐catalyzed site‐selective intermolecular amidation of saturated C (sp3)− H bonds is
reported. This mild protocol exhibits a predictable reactivity pattern to incorporate amide …