Cononsolvency of thermoresponsive polymers: where we are now and where we are going
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …
good solvents. This cosolvent-induced modulation of the polymer solubility has been …
Flory-type theories of polymer chains under different external stimuli
YA Budkov, MG Kiselev - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
In this Review, we present a critical analysis of various applications of the Flory-type theories
to a theoretical description of the conformational behavior of single polymer chains in dilute …
to a theoretical description of the conformational behavior of single polymer chains in dilute …
Relating side chain organization of PNIPAm with its conformation in aqueous methanol
D Mukherji, M Wagner, MD Watson, S Winzen… - Soft Matter, 2016 - pubs.rsc.org
Combining nuclear magnetic resonance (NMR), dynamic light scattering (DLS), and μs long
all-atom simulations with two million particles, we establish a delicate correlation between …
all-atom simulations with two million particles, we establish a delicate correlation between …
Poly(N-isopropylacrylamide) Microgels under Alcoholic Intoxication: When a LCST Polymer Shows Swelling with Increasing Temperature
S Backes, P Krause, W Tabaka, MU Witt… - ACS Macro …, 2017 - ACS Publications
Poly (N-isopropylacrylamide)(PNIPAM) microgel is a smart polymer that shows a volume
phase transition temperature (VPTT) at around 32° C in aqueous solutions, above which it …
phase transition temperature (VPTT) at around 32° C in aqueous solutions, above which it …
Stabilizing effect of TMAO on globular PNIPAM states: preferential attraction induces preferential hydration
MA Schroer, J Michalowsky, B Fischer… - Physical Chemistry …, 2016 - pubs.rsc.org
We study the effect of the organic co-solute trimethylamine N-oxide (TMAO) on the volume
phase transition of microgel particles made from poly (N-isopropylacrylamide)(PNIPAM) …
phase transition of microgel particles made from poly (N-isopropylacrylamide)(PNIPAM) …
Energetics and mechanisms of poly (N-isopropylacrylamide) phase transitions in water–methanol solutions
VY Grinberg, TV Burova, NV Grinberg… - …, 2020 - ACS Publications
The phase transitions of poly (N-isopropylacrylamide)(PNIPAM) in water–methanol mixed
solutions were studied in detail by high-sensitivity differential scanning calorimetry. From this …
solutions were studied in detail by high-sensitivity differential scanning calorimetry. From this …
Effect of Temperature on the Cononsolvency of Poly(N-isopropylacrylamide) (PNIPAM) in Aqueous 1-Propanol
HA Pérez-Ramírez, C Haro-Pérez… - ACS Applied Polymer …, 2019 - ACS Publications
The wide range of applications of poly (N-isopropylacrylamide)(PNIPAM) is based on the
temperature dependence of its coil-to-globule transition, which strongly relies on the solvent …
temperature dependence of its coil-to-globule transition, which strongly relies on the solvent …
Effects of enhanced flexibility and pore size distribution on adsorption-induced deformation of mesoporous materials
AL Kolesnikov, N Georgi, YA Budkov, J Möllmer… - Langmuir, 2018 - ACS Publications
Here, we present a new model of adsorption-induced deformation of mesoporous solids.
The model is based on a simplified version of local density functional theory in the …
The model is based on a simplified version of local density functional theory in the …
Co-solvent and temperature effect on conformation and hydration of polypropylene and polyethylene oxides in aqueous solutions
R Dahanayake, U Dahal, EE Dormidontova - Journal of Molecular Liquids, 2022 - Elsevier
Understanding the origin of conformational changes of water-soluble polymers, as affected
by external triggers such as temperature or co-solvent addition, is important from a …
by external triggers such as temperature or co-solvent addition, is important from a …
Conformation Transition of a Homopolymer Chain in Binary Mixed Solvents
On the basis of a minimal lattice model, we apply the Wang–Landau Monte Carlo (MC)
algorithm and a Flory-type mean-field theory to investigate the conformation of a …
algorithm and a Flory-type mean-field theory to investigate the conformation of a …