Polymerization of cyclopropenes: Taming the strain for the synthesis of controlled and sequence-regulated polymers

BR Elling, JK Su, Y Xia - Accounts of chemical research, 2020 - ACS Publications
Conspectus Cyclopropenes (CPEs) are highly strained cyclic olefins, yet there are
surprisingly limited examples leveraging their high strain energy for polymerization. In the …

Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Catalytic syntheses of degradable polymers via ring-opening metathesis copolymerization using vinyl ethers as chain transfer agents

A Mandal, I Mandal, AFM Kilbinger - Macromolecules, 2022 - ACS Publications
Commercially available Vince lactam and its derivatives are copolymerized with 2, 3-
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …

Catalytic living ring-opening metathesis polymerization with Grubbs' second-and third-generation catalysts

M Yasir, P Liu, IK Tennie, AFM Kilbinger - Nature chemistry, 2019 - nature.com
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number
of ruthenium complexes to the number of polymer chains synthesized are required. This can …

Catalytic Living Ring‐Opening Metathesis Polymerization Using Vinyl Ethers as Effective Chain‐Transfer Agents

A Mandal, I Mandal… - Angewandte Chemie …, 2023 - Wiley Online Library
A catalytic living ring‐opening metathesis copolymerization (ROMP) method is described
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …

Enzymatic and Chemical Approaches for Post‐Polymerization Modifications of Diene Rubbers: Current state and Perspectives

FA Soares, A Steinbüchel - Macromolecular Bioscience, 2021 - Wiley Online Library
Diene rubbers are polymeric materials which present elastic properties and have double
bonds in the macromolecular backbone after the polymerization process. Post …

A Cocatalyst Strategy to Enhance Ruthenium‐Mediated Metathesis Reactivity towards Electron‐Deficient Substrates

G Si, C Tan, M Chen, C Chen - … Chemie International Edition, 2022 - Wiley Online Library
Ruthenium‐mediated olefin metathesis has been widely applied for the synthesis of various
organic molecules and polymers. Inspired by the cocatalyst strategy for olefin …

Scalable Frontal Oligomerization: Insights from Advanced Mass Analysis

BA Suslick, DM Alzate-Sanchez, JS Moore - Macromolecules, 2022 - ACS Publications
Linear oligomers of dicyclopentadiene (DCPD) are reactive precursors for thermoplastic and
thermoset materials. Unlike the foul-smelling parent monomer, oligomers composed of …

End functionalization of polynorbornene with platinum–acetylide complexes utilizing a cross-metathesis reaction

S Uchiyama, T Sotani, T Mizokuro, H Sogawa… - …, 2022 - ACS Publications
The functionalization of the chain end of a polymer is gathering increasing attention in the
field of synthetic polymer chemistry. The present study is the first example to demonstrate the …

Practical route for catalytic ring-opening metathesis polymerization

I Mandal, AFM Kilbinger - JACS Au, 2022 - ACS Publications
Norbornene derivatives are typical monomers for ring-opening metathesis polymerization
(ROMP) for synthesizing highly functional polymers. However, the lack of catalytic methods …