Polymerization of cyclopropenes: Taming the strain for the synthesis of controlled and sequence-regulated polymers
Conspectus Cyclopropenes (CPEs) are highly strained cyclic olefins, yet there are
surprisingly limited examples leveraging their high strain energy for polymerization. In the …
surprisingly limited examples leveraging their high strain energy for polymerization. In the …
Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations
SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …
and these observations have driven polymer scientists to synthesize complex architectures …
Catalytic syntheses of degradable polymers via ring-opening metathesis copolymerization using vinyl ethers as chain transfer agents
Commercially available Vince lactam and its derivatives are copolymerized with 2, 3-
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …
Catalytic living ring-opening metathesis polymerization with Grubbs' second-and third-generation catalysts
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number
of ruthenium complexes to the number of polymer chains synthesized are required. This can …
of ruthenium complexes to the number of polymer chains synthesized are required. This can …
Catalytic Living Ring‐Opening Metathesis Polymerization Using Vinyl Ethers as Effective Chain‐Transfer Agents
A catalytic living ring‐opening metathesis copolymerization (ROMP) method is described
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …
Enzymatic and Chemical Approaches for Post‐Polymerization Modifications of Diene Rubbers: Current state and Perspectives
FA Soares, A Steinbüchel - Macromolecular Bioscience, 2021 - Wiley Online Library
Diene rubbers are polymeric materials which present elastic properties and have double
bonds in the macromolecular backbone after the polymerization process. Post …
bonds in the macromolecular backbone after the polymerization process. Post …
A Cocatalyst Strategy to Enhance Ruthenium‐Mediated Metathesis Reactivity towards Electron‐Deficient Substrates
G Si, C Tan, M Chen, C Chen - … Chemie International Edition, 2022 - Wiley Online Library
Ruthenium‐mediated olefin metathesis has been widely applied for the synthesis of various
organic molecules and polymers. Inspired by the cocatalyst strategy for olefin …
organic molecules and polymers. Inspired by the cocatalyst strategy for olefin …
Scalable Frontal Oligomerization: Insights from Advanced Mass Analysis
Linear oligomers of dicyclopentadiene (DCPD) are reactive precursors for thermoplastic and
thermoset materials. Unlike the foul-smelling parent monomer, oligomers composed of …
thermoset materials. Unlike the foul-smelling parent monomer, oligomers composed of …
End functionalization of polynorbornene with platinum–acetylide complexes utilizing a cross-metathesis reaction
S Uchiyama, T Sotani, T Mizokuro, H Sogawa… - …, 2022 - ACS Publications
The functionalization of the chain end of a polymer is gathering increasing attention in the
field of synthetic polymer chemistry. The present study is the first example to demonstrate the …
field of synthetic polymer chemistry. The present study is the first example to demonstrate the …
Practical route for catalytic ring-opening metathesis polymerization
I Mandal, AFM Kilbinger - JACS Au, 2022 - ACS Publications
Norbornene derivatives are typical monomers for ring-opening metathesis polymerization
(ROMP) for synthesizing highly functional polymers. However, the lack of catalytic methods …
(ROMP) for synthesizing highly functional polymers. However, the lack of catalytic methods …