Catalytic activity of faceted gold nanoparticles studied by a model reaction: evidence for substrate-induced surface restructuring
We present the analysis of the catalytic activity of gold nanoparticles in aqueous solution as
a function of temperature. As a model reaction, the reduction of p-nitrophenol (Nip) by …
a function of temperature. As a model reaction, the reduction of p-nitrophenol (Nip) by …
Colloid chemistry of nanocatalysts: A molecular view
K An, S Alayoglu, T Ewers, GA Somorjai - Journal of colloid and interface …, 2012 - Elsevier
Recent advances of a colloidal chemistry can offer great opportunities to fabricate and
design nanocatalysts. Comprehensive understanding of a basic concept and theory of the …
design nanocatalysts. Comprehensive understanding of a basic concept and theory of the …
Molecular studies of model surfaces of metals from single crystals to nanoparticles under catalytic reaction conditions. Evolution from prenatal and postmortem studies …
GA Somorjai, C Aliaga - Langmuir, 2010 - ACS Publications
Molecular level studies of metal crystal and nanoparticle surfaces under catalytic reaction
conditions at ambient pressures during turnover were made possible by the use of …
conditions at ambient pressures during turnover were made possible by the use of …
Towards understanding and predicting the hydronium ion catalyzed dehydration of cyclic-primary, secondary and tertiary alcohols
The varying steric environment of zeolites subtly influences the rates of hydronium-ion-
catalyzed dehydration of alcohols containing a cyclohexyl group in aqueous phase. The …
catalyzed dehydration of alcohols containing a cyclohexyl group in aqueous phase. The …
Catalytic hydrogenation of benzene to cyclohexene on Ru (0 0 0 1) from density functional theory investigations
The catalytic hydrogenation of benzene on transition metal surfaces is of fundamental
importance in petroleum industry. With the aim to improve its efficiency and particularly the …
importance in petroleum industry. With the aim to improve its efficiency and particularly the …
Concluding remarks on the theory of selective energy transfer and exemplification on a zeolite kinetics study
R Larsson - Monatshefte für Chemie-Chemical Monthly, 2013 - Springer
Some 30 years ago it was suggested that catalytic reactions that showed a
'compensation'effect were activated through a vibrational resonance between that one …
'compensation'effect were activated through a vibrational resonance between that one …
Enthalpy–entropy compensation effect in chemical kinetics and experimental errors: a numerical simulation approach
JF Perez-Benito, M Mulero-Raichs - The Journal of Physical …, 2016 - ACS Publications
Many kinetic studies concerning homologous reaction series report the existence of an
activation enthalpy–entropy linear correlation (compensation plot), its slope being the …
activation enthalpy–entropy linear correlation (compensation plot), its slope being the …
Kinetic modeling of the total oxidation of propane over anatase and vanadia sputter deposited catalysts
PM Heynderickx, JW Thybaut, H Poelman… - Applied Catalysis B …, 2009 - Elsevier
Using an innovative magnetron sputter deposition technique, a set of titania (anatase),
vanadia and vanadia–titania (anatase) based catalysts on porous SiO2 and non-porous …
vanadia and vanadia–titania (anatase) based catalysts on porous SiO2 and non-porous …
Cyclohexane dehydrogenation: Critical evaluation of parameter estimation procedures for kinetic modeling
R Kober, M Schwaab, E Barbosa-Coutinho… - Catalysis Today, 2025 - Elsevier
In the present paper a comparison between different parameter estimation procedures
commonly used for the kinetic modeling of chemical reaction is performed, based on …
commonly used for the kinetic modeling of chemical reaction is performed, based on …
Selective Heterogeneous transfer hydrogenation from tertiary amines to alkynes
Hydrogen transfer reactions from tertiary amines to phenyl-and alkyl-substituted alkynes
catalyzed by Pt and Pd supported on carbon are investigated. Evidence of a sequential two …
catalyzed by Pt and Pd supported on carbon are investigated. Evidence of a sequential two …