Catalytic activity of faceted gold nanoparticles studied by a model reaction: evidence for substrate-induced surface restructuring

S Wunder, Y Lu, M Albrecht, M Ballauff - Acs Catalysis, 2011 - ACS Publications
We present the analysis of the catalytic activity of gold nanoparticles in aqueous solution as
a function of temperature. As a model reaction, the reduction of p-nitrophenol (Nip) by …

Colloid chemistry of nanocatalysts: A molecular view

K An, S Alayoglu, T Ewers, GA Somorjai - Journal of colloid and interface …, 2012 - Elsevier
Recent advances of a colloidal chemistry can offer great opportunities to fabricate and
design nanocatalysts. Comprehensive understanding of a basic concept and theory of the …

Molecular studies of model surfaces of metals from single crystals to nanoparticles under catalytic reaction conditions. Evolution from prenatal and postmortem studies …

GA Somorjai, C Aliaga - Langmuir, 2010 - ACS Publications
Molecular level studies of metal crystal and nanoparticle surfaces under catalytic reaction
conditions at ambient pressures during turnover were made possible by the use of …

Towards understanding and predicting the hydronium ion catalyzed dehydration of cyclic-primary, secondary and tertiary alcohols

L Milakovic, PH Hintermeier, Q Liu, H Shi, Y Liu… - Journal of …, 2020 - Elsevier
The varying steric environment of zeolites subtly influences the rates of hydronium-ion-
catalyzed dehydration of alcohols containing a cyclohexyl group in aqueous phase. The …

Catalytic hydrogenation of benzene to cyclohexene on Ru (0 0 0 1) from density functional theory investigations

C Fan, YA Zhu, XG Zhou, ZP Liu - Catalysis today, 2011 - Elsevier
The catalytic hydrogenation of benzene on transition metal surfaces is of fundamental
importance in petroleum industry. With the aim to improve its efficiency and particularly the …

Concluding remarks on the theory of selective energy transfer and exemplification on a zeolite kinetics study

R Larsson - Monatshefte für Chemie-Chemical Monthly, 2013 - Springer
Some 30 years ago it was suggested that catalytic reactions that showed a
'compensation'effect were activated through a vibrational resonance between that one …

Enthalpy–entropy compensation effect in chemical kinetics and experimental errors: a numerical simulation approach

JF Perez-Benito, M Mulero-Raichs - The Journal of Physical …, 2016 - ACS Publications
Many kinetic studies concerning homologous reaction series report the existence of an
activation enthalpy–entropy linear correlation (compensation plot), its slope being the …

Kinetic modeling of the total oxidation of propane over anatase and vanadia sputter deposited catalysts

PM Heynderickx, JW Thybaut, H Poelman… - Applied Catalysis B …, 2009 - Elsevier
Using an innovative magnetron sputter deposition technique, a set of titania (anatase),
vanadia and vanadia–titania (anatase) based catalysts on porous SiO2 and non-porous …

Cyclohexane dehydrogenation: Critical evaluation of parameter estimation procedures for kinetic modeling

R Kober, M Schwaab, E Barbosa-Coutinho… - Catalysis Today, 2025 - Elsevier
In the present paper a comparison between different parameter estimation procedures
commonly used for the kinetic modeling of chemical reaction is performed, based on …

Selective Heterogeneous transfer hydrogenation from tertiary amines to alkynes

GJ Roeder, HR Kelly, G Yang, TJ Bauer, GL Haller… - ACS …, 2021 - ACS Publications
Hydrogen transfer reactions from tertiary amines to phenyl-and alkyl-substituted alkynes
catalyzed by Pt and Pd supported on carbon are investigated. Evidence of a sequential two …