Synthesis of Non-centrosymmetric, Metastable Rare-Earth Oxysulfides by Anionic Redox Topochemistry
Intercalation/deintercalation reactions enable introduction/removal of intercalants without
destructive structure transformation of host lattices. They are among the most versatile ways …
destructive structure transformation of host lattices. They are among the most versatile ways …
Chemical Perspectives of Heteroanionic Compounds and a Potential Playground for Multiferroics
Heteroanionic compounds, which host two or more different anions, have appeared as a
huge family of functional materials. Different from polyanionic compounds, there is no direct …
huge family of functional materials. Different from polyanionic compounds, there is no direct …
Topochemical Anionic Subunit Insertion Reaction for Constructing Nanoparticles of Layered Oxychalcogenide Intergrowth Structures
Intergrowth compounds contain alternating layers of chemically distinct subunits that yield
composition-tunable synergistic properties. Synthesizing nanoparticles of intergrowth …
composition-tunable synergistic properties. Synthesizing nanoparticles of intergrowth …
Photocatalytic and Photocurrent Responses to Visible Light of the Lone-Pair-Based Oxysulfide Sr6Cd2Sb6S10O7
S Al Bacha, S Saitzek, EE McCabe… - Inorganic …, 2022 - ACS Publications
We present a combined experimental and computational study on the recently reported
oxysulfide Sr6Cd2Sb6S10O7. Our spectroscopy and photoelectrochemical measurements …
oxysulfide Sr6Cd2Sb6S10O7. Our spectroscopy and photoelectrochemical measurements …
Laser power and high-temperature dependent Raman studies of layered bismuth and copper-based oxytellurides for optoelectronic applications
Layered metal oxychalcogenide materials have gained significant attention in recent years
due to their numerous applications in various emerging fields. The bismuth (Bi) based …
due to their numerous applications in various emerging fields. The bismuth (Bi) based …
High-Quality Ultrathin Gd2O2S Nanosheets with Oxygen Vacancy-Decorated rGO for Enhanced Electromagnetic Wave Absorption
N Li, B Wen, X Li, A Zuo, S Yang, S Ding… - ACS Applied Materials …, 2023 - ACS Publications
The development of extreme performance and multifunctional electromagnetic (EM) wave
absorption materials is essential to eliminating undesirable frequency EM pollution. As a …
absorption materials is essential to eliminating undesirable frequency EM pollution. As a …
Quaternary Rare-Earth Oxyselenides RE4Ga2Se7O2 (RE = Pr, Nd) with Trigonal Bipyramidal GaSe5 Units: Evaluation of Optical, Thermoelectric, and …
Phase-pure samples and single crystals of the rare-earth oxyselenides RE 4Ga2Se7O2
(RE= Pr, Nd) were prepared by reactions at 950° C. They adopt a new structure type …
(RE= Pr, Nd) were prepared by reactions at 950° C. They adopt a new structure type …
Ba6Ge2Se12 and Ba7Ge2Se17: Two Centrosymmetric Barium Seleno-Germanates with Polyatomic Anion Disorder
LT Menezes, BN Richtik, A Assoud… - Inorganic …, 2022 - ACS Publications
Herein, the crystal structures and physical properties of two previously unreported barium
seleno-germanates, Ba6Ge2Se12 and Ba7Ge2Se17, are presented. Ba6Ge2Se12 adopts …
seleno-germanates, Ba6Ge2Se12 and Ba7Ge2Se17, are presented. Ba6Ge2Se12 adopts …
La4Ga2Se6O3: A Rare-Earth Oxyselenide Built from One-Dimensional Strips
The oxyselenide La4Ga2Se6O3 was obtained by reaction in NaCl flux. Its monoclinic crystal
structure (space group C 2/c, a= 21.2832 (13) Å, b= 11.6272 (7) Å, c= 6.0006 (4) Å, β …
structure (space group C 2/c, a= 21.2832 (13) Å, b= 11.6272 (7) Å, c= 6.0006 (4) Å, β …
[HTML][HTML] Structure and compositional trends in alkali-metal containing titanium and vanadium oxide chalcogenides and the new van der Waals phase Ti2Te2O
ND Kelly, SJ Clarke - Journal of Solid State Chemistry, 2023 - Elsevier
We report the solid-state synthesis of all eighteen layered oxide chalcogenides in the
structural family AM 2 Q 2 O (A= K/Rb/Cs; M= Ti/V; Q= S/Se/Te), allowing the determination …
structural family AM 2 Q 2 O (A= K/Rb/Cs; M= Ti/V; Q= S/Se/Te), allowing the determination …